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JEE Advanced 2014Paper 1
Exam
JEE Advanced
Year
2014
Paper
Paper 1
Subject
Chemistry
Chapter
Redox Reactions

JEE Advanced 2014 · Paper 1 · Chemistry · Redox Reactions

Consider the following list of reagents: Acidified K _ 2 C r _ 2 O...

Consider the following list of reagents: Acidified K2Cr2O7{K}_{2}C{r}_{2}{O}_{7} , alkaline KMnO4,CuSO4,H2O2,Cl2,O3,FeCl3,HNO3KMn{O}_{4}, CuS{O}_{4}, {H}_{2}{O}_{2}, C{l}_{2}, {O}_{3}, FeC{l}_{3}, HN{O}_{3} and Na2S2O3N{a}_{2}{S}_{2}{O}_{3} . The total number of reagents that can oxidise aqueous iodide to iodine is

Correct answer

7

Step-by-step solution

K2Cr2O7,CuSO4,H2O2,Cl2,O3,FeCl3,HNO3{K}_{2}C{r}_{2}{O}_{7}, CuS{O}_{4}, {H}_{2}{O}_{2}, C{l}_{2}, {O}_{3}, FeC{l}_{3}, HN{O}_{3}
K2Cr2O7+7H2SO4+6KI→4K2SO4+Cr2(SO4)3+3I2+7H2O{K}_{2}C{r}_{2}{O}_{7} + 7{H}_{2}S{O}_{4} + 6KI \to 4{K}_{2}S{O}_{4} + C{r}_{2}{\left(S{O}_{4}\right)}_{3} + 3{I}_{2} + 7{H}_{2}O
2CuSO4+4KI→Cu2I2+I2+2K2SO42CuS{O}_{4} + 4KI \to C{u}_{2}{I}_{2} + {I}_{2} + 2{K}_{2}S{O}_{4}
H2O2+2KI→I2+2KOH{H}_{2}{O}_{2} + 2KI \to {I}_{2} + 2KOH
Cl2+2KI→2KCl+I2C{l}_{2} + 2KI \to 2KCl + {I}_{2}
O3+2KI+H2O→2KOH+I2+O2{O}_{3} + 2KI + {H}_{2}O \to 2KOH + {I}_{2} + {O}_{2}
2FeCl3+2KI→2FeCl2+I2+2KCl2FeC{l}_{3} + 2KI \to 2FeC{l}_{2} + {I}_{2} + 2KCl
8HNO3+6KI→6KNO3+2NO+4H2O+3I28HN{O}_{3} + 6KI \to 6KN{O}_{3} + 2NO + 4{H}_{2}O + 3{I}_{2}
2KMnO4+KI+H2O→KIO3+2MnO2+2KOH2KMn{O}_{4} + KI + {H}_{2}O \to KI{O}_{3} + 2Mn{O}_{2} + 2KOH
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