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JEE Advanced 2014Paper 1
Exam
JEE Advanced
Year
2014
Paper
Paper 1
Subject
Chemistry
Chapter
Redox Reactions

JEE Advanced 2014 · Paper 1 · Chemistry · Redox Reactions

For the reaction: I ^ - + Cl O _ 3 ^ - + H _ 2 S O _ 4 → C l ^ - +...

For the reaction:
I−+ClO3−+H2SO4→Cl−+HSO4−+I2{I}^{-} + Cl{O}_{3}^{-} + {H}_{2}S{O}_{4} \to C{l}^{-} + HS{O}_{4}^{-} + {I}_{2}
The correct statement(s) in the balanced equation is/are:

Options

  1. AStoichiometric coefficient of HSO4−HS{O}_{4}^{-} is 6.
  2. BIodide is oxidized.
  3. CSulphur is reduced.
  4. DH2O{H}_{2}O is one of the products.

Correct answer

A. Stoichiometric coefficient of HSO4−HS{O}_{4}^{-} is 6.

Step-by-step solution

The balanced equation is,
ClO3−+6I−+6H2SO4→3I2+Cl−+6HSO4−+3H2OCl{O}_{3}^{-} + 6{I}^{-} + 6{H}_{2}S{O}_{4} \to 3{I}_{2} + C{l}^{-} + 6HS{O}_{4}^{-} + 3{H}_{2}O

Here, in this reaction,

HSO4−{HSO}_{4}^{-} is in one of the products, and by balancing the reaction, we get its stiochiometric coefficient as 6.

Oxidation number of iodine in reactant side is −1- 1 and it is oxidised to I2with0{I}_{2}with0 oxidation number in product side.

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