Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Advanced2015ChemistrySolutionsActual

If the freezing point of a 0.01 molal aqueous solution of a cobalt (III) chloride-ammonia complex (which behaves as a strong electrolyte) is - 0.0558 o C , the number of chloride(s) in the coordination sphere of the complex is [ K f   o f   w a t e r = 1.86   K   k g   m o l - 1 ]

Correct answer

1

Step-by-step solution

∆ T f = K f × i × m 0.0558 = 1.86 × i × 0.01 i = 3 Given complex behaves as a strong electrolyte α = 100 % n = 3 (no. of particles given by complex) ∴ complex is C o N H 3 5 C l C l 2 no. of C l - ions in the co-ordination sphere of the complex = 1

Practice Solutions on Quantrex Academy →

More from Solutions

In a solvent S , a compound B is partially dissociated into C and D as given below: B 2 C + 2 D B , C and D are non-volatile in nature. The molar mass of B is 10 times the molar ma 2026Passage: Two volatile liquids A and B form an ideal solution. Consider a 5 molal solution of B in A inside a closed container having a total vapour pressure of 100 mm Hg at 300 K. 2026Passage: Two volatile liquids A and B form an ideal solution. Consider a 5 molal solution of B in A inside a closed container having a total vapour pressure of 100 mm Hg at 300 K. 2026Given below are two statements: Given: Molar mass of C, H, O, Cl are 12, 1, 16 and 35.5 g mol ⁻¹ , respectively. Statement I: In 30 % (w/w) solution of methanol in CCl ₄ (at T K), 2026Which of the following statements are not correct? A. For water, magnitude of K_b is more than the magnitude of K_f . B. The elevation in boiling point of water when a non-volatile 2026Given below are two statements : Statement I : H₂ O molecules move from the chamber 1 to chamber 2 . Statement II : The osmotic pressure of a solution prepared by dissolving 50 mg 2026When 0.25 moles of a non-volatile, non-ionizable solute was dissolved in 1 mole of a solvent the vapor pressure of solution was x % of vapor pressure of pure solvent. What is x % ? 202620 g hemoglobin in a 1 L aqueous solution (A) at 300 K is separated from pure water by semi permeable membrane. At equilibrium the height of solution in a tube dipped in a solution 2026 Full Solutions list All JEE Advanced PYQs