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JEE Advanced 2023Paper 2
Exam
JEE Advanced
Year
2023
Paper
Paper 2
Subject
Chemistry
Chapter
Structure of Atom

JEE Advanced 2023 · Paper 2 · Chemistry · Structure of Atom

For He ^ + , a transition takes place from the orbit of radius 105...

For He+{He}^{+}, a transition takes place from the orbit of radius 105.8pm105 . 8pm to the orbit of radius 26.45pm26 . 45pm. The wavelength (in nmnm ) of the emitted photon during the transition is

Bohr radius, a=52.9pma = 52 . 9pm
Rydberg constant, RH=2.2×10−18J{R}_{H} = 2 . 2 \times {10}^{- 18}J
Planck's constant, h=6.6×10−34Jsh = 6 . 6 \times {10}^{- 34}Js
Speed of light, c=3×108ms−1c = 3 \times {10}^{8}{ms}^{- 1} ]

Correct answer

30

Step-by-step solution

The radius of the nth orbit can be represented as,

r=52.9×n2zpmr = 52 . 9 \times \dfrac{{n}^{2}}{z}pm

∴105.8=52.9×n22∴n2=2∴ 105 . 8 = \dfrac{52 . 9 \times {n}^{2}}{2} ∴ {n}_{2} = 2

and 26.45=52.9×n22∴n1=126 . 45 = 52 . 9 \times \dfrac{{n}^{2}}{2} ∴ {n}_{1} = 1

∵ΔE=RHhC×z2[1n12−1n22]∵ \Delta E = {R}_{H}hC \times {z}^{2}\left[1{n}_{1}^{2} - 1{n}_{2}^{2}\right]

hcλ=RHhC×z2[1n12−1n22]\dfrac{hc}{\lambda} = {R}_{H}hC \times {z}^{2}\left[1{n}_{1}^{2} - 1{n}_{2}^{2}\right]

6.6×10−34×3×108λ=2.2×10−18×4×[11−14]\dfrac{6 . 6 \times {10}^{- 34} \times 3 \times {10}^{8}}{\lambda} = 2 . 2 \times {10}^{- 18} \times 4 \times \left[\dfrac{1}{1} - \dfrac{1}{4}\right]

6.6×10−34×3×108λ=2.2×10−18×4×34\dfrac{6 . 6 \times {10}^{- 34} \times 3 \times {10}^{8}}{\lambda} = 2 . 2 \times {10}^{- 18} \times 4 \times \dfrac{3}{4}

∴λ=300A∴ \lambda = 300A

∴λ=30nm∴ \lambda = 30nm

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