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JEE Advanced 2006
Exam
JEE Advanced
Year
2006
Subject
Chemistry
Chapter
Structure of Atom

JEE Advanced 2006 · Chemistry · Structure of Atom

According to Bohr's theory E_n= Total energy, K_n= Kinetic energy,...

According to Bohr's theory En=E_n= Total energy, Kn=K_n= Kinetic energy, Vn=V_n= Potential energy, rn=r_n= Radius of nnth orbit According to Bohr's theory E_n= Total energy, K_n= Kinetic energy, V_n= Potential energy, r_n= Radius of n th orbit

Options

  1. A(A) R, (B) Q, (C) P, (D) Q
  2. B(A) S, (B) R, (C) R, (D) S
  3. C(A) R, (B) Q, (C) P, (D) S
  4. D(A) S, (B) P, (C) R, (D) Q

Correct answer

C. (A) R, (B) Q, (C) P, (D) S

Step-by-step solution

According to Bohr's theory, Total energy is En=Kn+VnE_n=K_n+V_n Kinetic energy =Kn=18πε0⋅Ze2r=K_n=\frac{1}{8 \pi \varepsilon_0} \cdot \frac{Z e^2}{r} Potential energy =Vn=14πε0⋅Ze2r∴En=18πε0⋅Ze2r−14πε0⋅Ze2r=V_n=\frac{1}{4 \pi \varepsilon_0} \cdot \frac{Z e^2}{r}\therefore \quad E_n=\frac{1}{8 \pi \varepsilon_0} \cdot \frac{Z e^2}{r}-\frac{1}{4 \pi \varepsilon_0} \cdot \frac{Z e^2}{r} Radius of nnth orbit \left(r_n\right)=\frac{n^2 h^2 \varepsilon_0}{\pi m Z e^2}En=−E_n=-\frac{m e^4}{8 \varepsilon_0^2 h^2} \times \frac{1}{n^2} (A)A)\frac{V_n}{K_n}=\frac{-\frac{1}{4 \pi \varepsilon_0} \cdot \frac{Z e^2}{r}}{\frac{1}{8 \pi \varepsilon_0} \cdot \frac{Z e^2}{r}}=-2Hence,Hence,(A)matchwithmatch with(R).(B). (B)E_n \propto \frac{1}{n^2}ororE_n \propto \frac{1}{r_n}RadiusofRadius ofnthorbitth orbitr_n \propto E_n^x\therefore \quad x=-1Hence, (B) matchwith(Q).(C)Angularmomentum=with (Q). (C) Angular momentum =\frac{h}{2 \pi}l(l+1)l=0,1,2,…\sqrt{l(l+1) l}=0,1,2, \ldots For the lower orbit n=1∴l=0andm=0Hence,angularmomentumofn=1\therefore \quad l=0 and m=0 Hence, angular momentum oflowest orbit =\frac{h}{2 \pi} \sqrt{0(0 H)}=0(C)matchwith(P)(D)(C) match with (P) (D)\frac{1}{r^n} \propto Z^yasasr_n \propto \frac{1}{Z} \therefore y=1 Hence, (D) match with (S).
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