JEE Advanced 2026Paper 1
- Exam
- JEE Advanced
- Year
- 2026
- Paper
- Paper 1
- Subject
- Chemistry
- Chapter
- Thermodynamics (C)
JEE Advanced 2026 · Paper 1 · Chemistry · Thermodynamics (C)
An ideal gas ( 0.5 mol), initially at 2 bar pressure, is compressed...
An ideal gas ( mol), initially at bar pressure, is compressed at a constant temperature of K in two steps: first, against a constant external pressure of bar (), and then against constant external pressure of bar. At each step, the compression is stopped only when the pressure of the gas becomes equal to the external pressure. The total work done on the gas in these steps is . Considering all possible values of () and taking the gas constant as (in J K mol), the minimum value of (in J) is
Options
- A
- B
- C
- D
Correct answer
B.
Step-by-step solution
Let the initial, intermediate, and final volumes of the gas be , , and respectively.
Using the ideal gas equation , we have:
The work done on the gas during the first step against a constant external pressure is:
The work done on the gas during the second step against a constant external pressure of bar is:
The total work done on the gas is:
To find the minimum value of , we need to minimize the expression \left( \dfrac{P}{2} + \dfrac{8}{P} \right)\dfrac{P}{2} + \dfrac{8}{P} \ge 2 \sqrt{\dfrac{P}{2} \times \dfrac{8}{P}} = 2 \sqrt{4} = 44\dfrac{P}{2} = \dfrac{8}{P} \Rightarrow P^2 = 16 \Rightarrow P = 4P(2 < P < 8)W_\min = nRT (4 - 2) = 2nRTn = 0.5T = 600W_\min = 2 \times 0.5 \times R \times 600 = 600R600R
Using the ideal gas equation , we have:
The work done on the gas during the first step against a constant external pressure is:
The work done on the gas during the second step against a constant external pressure of bar is:
The total work done on the gas is:
To find the minimum value of , we need to minimize the expression \left( \dfrac{P}{2} + \dfrac{8}{P} \right)\dfrac{P}{2} + \dfrac{8}{P} \ge 2 \sqrt{\dfrac{P}{2} \times \dfrac{8}{P}} = 2 \sqrt{4} = 44\dfrac{P}{2} = \dfrac{8}{P} \Rightarrow P^2 = 16 \Rightarrow P = 4P(2 < P < 8)W_\min = nRT (4 - 2) = 2nRTn = 0.5T = 600W_\min = 2 \times 0.5 \times R \times 600 = 600R600R