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JEE Advanced 2026Paper 1
Exam
JEE Advanced
Year
2026
Paper
Paper 1
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Advanced 2026 · Paper 1 · Chemistry · Thermodynamics (C)

An ideal gas ( 0.5 mol), initially at 2 bar pressure, is compressed...

An ideal gas (0.50.5 mol), initially at 22 bar pressure, is compressed at a constant temperature of 600600 K in two steps: first, against a constant external pressure of PP bar (2<P<82 < P < 8), and then against constant external pressure of 88 bar. At each step, the compression is stopped only when the pressure of the gas becomes equal to the external pressure. The total work done on the gas in these steps is WW. Considering all possible values of PP (2<P<82 < P < 8) and taking the gas constant as RR (in J K−1^{-1} mol−1^{-1}), the minimum value of ∣W∣|W| (in J) is

Options

  1. A207R207R
  2. B600R600R
  3. C630R630R
  4. D900R900R

Correct answer

B. 600R600R

Step-by-step solution

Let the initial, intermediate, and final volumes of the gas be V1V_1, V2V_2, and V3V_3 respectively.

Using the ideal gas equation V=nRTPV = \dfrac{nRT}{P}, we have:
V1=nRT2V_1 = \dfrac{nRT}{2}
V2=nRTPV_2 = \dfrac{nRT}{P}
V3=nRT8V_3 = \dfrac{nRT}{8}

The work done on the gas during the first step against a constant external pressure PP is:
W1=−Pext,1(V2−V1)=−P(nRTP−nRT2)=nRT(P2−1)W_1 = -P_{ext,1}(V_2 - V_1) = -P \left( \dfrac{nRT}{P} - \dfrac{nRT}{2} \right) = nRT \left( \dfrac{P}{2} - 1 \right)

The work done on the gas during the second step against a constant external pressure of 88 bar is:
W2=−Pext,2(V3−V2)=−8(nRT8−nRTP)=nRT(8P−1)W_2 = -P_{ext,2}(V_3 - V_2) = -8 \left( \dfrac{nRT}{8} - \dfrac{nRT}{P} \right) = nRT \left( \dfrac{8}{P} - 1 \right)

The total work done on the gas is:
W=W1+W2=nRT(P2−1)+nRT(8P−1)=nRT(P2+8P−2)W = W_1 + W_2 = nRT \left( \dfrac{P}{2} - 1 \right) + nRT \left( \dfrac{8}{P} - 1 \right) = nRT \left( \dfrac{P}{2} + \dfrac{8}{P} - 2 \right)

To find the minimum value of WW, we need to minimize the expression \left( \dfrac{P}{2} + \dfrac{8}{P} \right).<br><br>UsingtheAM−GMinequality:<br>.<br><br>Using the AM-GM inequality:<br>\dfrac{P}{2} + \dfrac{8}{P} \ge 2 \sqrt{\dfrac{P}{2} \times \dfrac{8}{P}} = 2 \sqrt{4} = 4<br><br>Theminimumvalueis<br><br>The minimum value is4,whichoccurswhen, which occurs when\dfrac{P}{2} = \dfrac{8}{P} \Rightarrow P^2 = 16 \Rightarrow P = 4bar.Thisvalueofbar. This value ofPlieswithinthegivenrangelies within the given range(2 < P < 8).<br><br>Substitutingthisminimumvaluebackintotheworkequation:<br>.<br><br>Substituting this minimum value back into the work equation:<br>W_\min = nRT (4 - 2) = 2nRT<br><br>Given<br><br>Givenn = 0.5molandmol andT = 600K:<br>K:<br>W_\min = 2 \times 0.5 \times R \times 600 = 600R<br><br>Answer:<br><br>Answer:600R
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