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JEE Main 20266 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
6 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2026 · 6 April · Morning Shift · Chemistry · Thermodynamics (C)

Arrange the following isothermal processes in order of the...

Arrange the following isothermal processes in order of the magnitude of the work (p−Vp - V) involved between states 11 and 22.
A. Expansion in single stage wAw_A
B. Expansion in multi stages wBw_B
C. Compression in single stage wCw_C
D. Compression in multi stages wDw_D

Choose the correct option.

Options

  1. A∣wB∣>∣wA∣>∣wC∣>∣wD∣|w_B| > |w_A| > |w_C| > |w_D|
  2. B∣wC∣>∣wD∣>∣wA∣>∣wB∣|w_C| > |w_D| > |w_A| > |w_B|
  3. C∣wC∣>∣wD∣>∣wB∣>∣wA∣|w_C| > |w_D| > |w_B| > |w_A|
  4. D∣wB∣>∣wA∣>∣wD∣>∣wC∣|w_B| > |w_A| > |w_D| > |w_C|

Correct answer

C. ∣wC∣>∣wD∣>∣wB∣>∣wA∣|w_C| > |w_D| > |w_B| > |w_A|

Step-by-step solution

Let State 11 have pressure P1P_1 and volume V1V_1, and State 22 have pressure P2P_2 and volume V2V_2. For an isothermal expansion, V2>V1V_2 > V_1 and P1>P2P_1 > P_2.

For expansion from State 11 to State 22:
In a single-stage expansion, the external pressure is constant at the final pressure P2P_2. The magnitude of work is ∣wA∣=P2(V2−V1)|w_A| = P_2(V_2 - V_1).
In a multi-stage expansion, the external pressure is reduced in steps, keeping it closer to the internal pressure of the gas. The work done by the gas increases with the number of stages, reaching a maximum for a reversible process (∣wrev∣|w_{rev}|). Thus, ∣wrev∣>∣wB∣>∣wA∣|w_{rev}| > |w_B| > |w_A|.

For compression from State 22 to State 11:
In a single-stage compression, the external pressure is constant at the final pressure P1P_1. The magnitude of work is ∣wC∣=P1(V2−V1)|w_C| = P_1(V_2 - V_1).
In a multi-stage compression, the external pressure is increased in steps. The work done on the gas decreases with the number of stages, reaching a minimum for a reversible process (∣wrev∣|w_{rev}|). Thus, ∣wC∣>∣wD∣>∣wrev∣|w_C| > |w_D| > |w_{rev}|.

Since P1>P2P_1 > P_2, the single-stage compression work ∣wC∣|w_C| is the largest, and the single-stage expansion work ∣wA∣|w_A| is the smallest. The reversible work magnitude ∣wrev∣|w_{rev}| is the same for both expansion and compression between the same states.

Combining these inequalities, we get:
∣wC∣>∣wD∣>∣wrev∣>∣wB∣>∣wA∣|w_C| > |w_D| > |w_{rev}| > |w_B| > |w_A|

Therefore, the correct order of the magnitude of work is ∣wC∣>∣wD∣>∣wB∣>∣wA∣|w_C| > |w_D| > |w_B| > |w_A|.

Answer: ∣wC∣>∣wD∣>∣wB∣>∣wA∣|w_C| > |w_D| > |w_B| > |w_A|
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