JEE Main 202623 JanuaryMorning Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 23 January
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Aldehydes and Ketones
JEE Main 2026 · 23 January · Morning Shift · Chemistry · Aldehydes and Ketones
' x ' is the product which is obtained from propanenitrile and...
' ' is the product which is obtained from propanenitrile and stannous chloride in the presence of hydrochloric acid followed by hydrolysis. ' ' is the product which is obtained from the but-2-ene by the ozonolysis followed by hydrolysis. From the following, which product is not obtained when one mole of ' ' and one mole of ' ' react with each other in the presence of alkali followed by heating?
Options
- A2-Methylpent-2-enal
- BPent-2-enal
- C2-Methylbut-2-enal
- D3-Methylbut-2-enal
Correct answer
D. 3-Methylbut-2-enal
Step-by-step solution
Product is obtained by the Stephen reduction of propanenitrile ().
(Propanal).
Product is obtained by the reductive ozonolysis of but-2-ene ().
(Ethanal).
When propanal () and ethanal () react in the presence of alkali followed by heating, they undergo cross-aldol condensation.
Possible products are:
1. Self-aldol of propanal: (2-Methylpent-2-enal).
2. Self-aldol of ethanal: (But-2-enal).
3. Cross-aldol (Ethanal as nucleophile): (Pent-2-enal).
4. Cross-aldol (Propanal as nucleophile): (2-Methylbut-2-enal).
Comparing with the options, 3-Methylbut-2-enal is not formed in any of these reactions.
(Propanal).
Product is obtained by the reductive ozonolysis of but-2-ene ().
(Ethanal).
When propanal () and ethanal () react in the presence of alkali followed by heating, they undergo cross-aldol condensation.
Possible products are:
1. Self-aldol of propanal: (2-Methylpent-2-enal).
2. Self-aldol of ethanal: (But-2-enal).
3. Cross-aldol (Ethanal as nucleophile): (Pent-2-enal).
4. Cross-aldol (Propanal as nucleophile): (2-Methylbut-2-enal).
Comparing with the options, 3-Methylbut-2-enal is not formed in any of these reactions.