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JEE Main 202312 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
12 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Aldehydes and Ketones

JEE Main 2023 · 12 April · Morning Shift · Chemistry · Aldehydes and Ketones

The mass of NH _ 3 produced when 131 . 8kg of cyclohexane...

The mass of NH3{NH}_{3} produced when 131.8kg131 . 8kg of cyclohexane carbaldehyde undergoes Tollen’s test is _____ kgkg. (Nearest Integer)

Molar mass of C=12g/molC = 12g / mol

N=14g/molN = 14g / mol

O=16g/molO = 16g / mol

Correct answer

0

Step-by-step solution

RCHO+2[Ag(NH3)2]OH→RCOONH4+2Ag+3NH3+H2ORCHO + 2\left[Ag{\left({NH}_{3}\right)}_{2}\right]OH \to {RCOONH}_{4} + 2Ag + 3{NH}_{3} + {H}_{2}O

The RCHORCHO is cyclohexane carbaldehyde (C6H11CHO{C}_{6}{H}_{11}CHO). The molar mass is112g112g.

The number of moles of cyclohexane carbaldehyde=131.8×103112=1.176×103mol= \dfrac{131 . 8 \times {10}^{3}}{112} = 1 . 176 \times {10}^{3}mol

11 mole of aldehyde produces 33 moles of NH3{NH}_{3}

1.176×1031 . 176 \times {10}^{3} mol aldehyde will produce

=3×1.176×103= 3 \times 1 . 176 \times {10}^{3} moles of NH3{NH}_{3}

Mass of NH3{NH}_{3} produced =3×1.176×103×17= 3 \times 1 . 176 \times {10}^{3} \times 17

=59.97×103g= 59 . 97 \times {10}^{3}g

≈60kg\approx 60kg

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