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JEE Main 202229 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
29 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Aldehydes and Ketones

JEE Main 2022 · 29 July · Evening Shift · Chemistry · Aldehydes and Ketones

The number of stereoisomers formed in a reaction of (±)PhC (= O)C...

The number of stereoisomers formed in a reaction of (±)PhC\left(\pm\right)PhC\left(= O\right)C(OH)(CN)Ph\left(OH\right)\left(CN\right)Ph with HCNHCN isThe number of stereoisomers formed in a reaction of (±)PhC (= O)C (OH)(CN)Ph with HCN is

Correct answer

3

Step-by-step solution

Aldehydes and ketones undergo reaction with HCN to produce cyanohydrins. The reaction progresses very slowly by using pure hydrogen cyanide. Hence, base as a catalyst helps to speed up the reaction. This is an example of nucleophilic addition reaction.

here we are given racemic mixture of optically active compound. The attacking nucleophile can attack on carbonyl carbon from either side forming a new chiral carbon. So, in product there will be two chiral carbon but it is symmetrical. So, number of stereoisomers will be 3 only.

The number of stereoisomers formed in a reaction of (±)PhC (= O)C (OH)(CN)Ph with HCN is

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