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JEE Main 20199 AprilEvening Shift
Exam
JEE Main
Year
2019
Date
9 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Aldehydes and Ketones

JEE Main 2019 · 9 April · Evening Shift · Chemistry · Aldehydes and Ketones

In the following reaction carbonyl compound + MeOH HCl ⇌ acetal...

In the following reaction
carbonyl compound +MeOH⇌HClacetal+ MeOH\overset{HCl}{⇌}acetal

Rate of the reaction is the highest for:In the following reaction carbonyl compound + MeOH HCl ⇌ acetal Rate of the reaction is the highest for:

Options

  1. AAcetone as substrate and methanol in stoichiometric amount
  2. BPropanal as substrate and methanol in excess
  3. CPropanal as substrate and methanol in stoichiometric amount
  4. D

    Acetone as substrate and methanol in excess

Correct answer

B. Propanal as substrate and methanol in excess

Step-by-step solution

Acetal is form from the reaction of aldehyde with excess of MeOHMeOH
In the following reaction carbonyl compound + MeOH HCl ⇌ acetal Rate of the reaction is the highest for:

Formation of an acetal occurs when the hydroxyl group of a hemiacetal becomes protonated and is lost as water. The carbocation that is produced is then rapidly attacked by a molecule of alcohol. Loss of the proton from the attached alcohol gives the acetal.

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