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JEE Main 20146 April
Exam
JEE Main
Year
2014
Date
6 April
Subject
Chemistry
Chapter
Aldehydes and Ketones

JEE Main 2014 · 6 April · Chemistry · Aldehydes and Ketones

In the reaction, CH _ 3 COOH LiAlH _ 4 → A PCl _ 5 → B Alc. KOH → C...

In the reaction,

CH3COOH→LiAlH4A→PCl5B→Alc. KOHC{\text{CH}}_{3} \text{COOH} \overset{{\text{LiAlH}}_{4}}{\to} \text{A} \overset{{\text{PCl}}_{5}}{\to} \text{B} \overset{\text{Alc. KOH}}{\to} \text{C},

the product C is :

Options

  1. AAcetaldehyde
  2. BAcetylene
  3. CEthylene
  4. DAcetyl chloride

Correct answer

C. Ethylene

Step-by-step solution

LiAlH4{LiAlH}_{4} is a reducing agent and reduces carboxylic acid to alcohol.

CH3COOH→LiAlH4CH3−CH2−OH{\text{CH}}_{3} COOH \overset{{\text{LiAlH}}_{4}}{\to} {\text{CH}}_{3} - {\text{CH}}_{2} - \text{OH}
(A)

→PCl5CH3−CH2−Cl→KOHalcCH2=CH2\overset{{\text{PCl}}_{5}}{\to} {\text{CH}}_{3} - {\text{CH}}_{2} - \text{Cl} \mathop{\to}_{\text{KOH}}^{\text{alc}} {\text{CH}}_{2} = {\text{CH}}_{2}

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