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JEE Main 20264 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Biomolecules

JEE Main 2026 · 4 April · Evening Shift · Chemistry · Biomolecules

A D-aldotetrose on oxidation with concentrated HNO_3 resulted in...

A D-aldotetrose on oxidation with concentrated HNO3HNO_3 resulted in optically inactive dicarboxylic acid. The structure of the D-aldotetrose is:A D-aldotetrose on oxidation with concentrated HNO_3 resulted in optically inactive dicarboxylic acid. The structure ofA D-aldotetrose on oxidation with concentrated HNO_3 resulted in optically inactive dicarboxylic acid. The structure ofA D-aldotetrose on oxidation with concentrated HNO_3 resulted in optically inactive dicarboxylic acid. The structure ofA D-aldotetrose on oxidation with concentrated HNO_3 resulted in optically inactive dicarboxylic acid. The structure ofA D-aldotetrose on oxidation with concentrated HNO_3 resulted in optically inactive dicarboxylic acid. The structure of

Options

  1. AThe concentration of dissolved oxygen (DO) in cold water can go upto
  2. BThe concentration of dissolved oxygen (DO) in cold water can go upto
  3. CThe concentration of dissolved oxygen (DO) in cold water can go upto
  4. DThe concentration of dissolved oxygen (DO) in cold water can go upto

Correct answer

C. The concentration of dissolved oxygen (DO) in cold water can go upto

Step-by-step solution

For a carbohydrate to be classified as a D-sugar, the hydroxyl (−OH-OH) group on the lowest chiral carbon (C3 in the case of an aldotetrose) must be on the right side in its Fischer projection. This eliminates options (A) and (B), which are L-sugars.

Oxidation of an aldotetrose with concentrated HNO3HNO_3 converts both the aldehyde (−CHO-CHO) group at C1 and the primary alcohol (−CH2OH-CH_2OH) group at C4 into carboxylic acid (−COOH-COOH) groups, yielding a dicarboxylic acid (tartaric acid).

The problem states that the resulting dicarboxylic acid is optically inactive. This implies that the product must be a meso compound, which requires a plane of symmetry. For the dicarboxylic acid to possess a plane of symmetry, the −OH-OH groups on C2 and C3 must be on the same side in the Fischer projection.

Looking at the D-sugars:
Option (C) is D-erythrose. Upon oxidation, it forms meso-tartaric acid, which has a plane of symmetry and is optically inactive.
Option (D) is D-threose. Upon oxidation, it forms an optically active tartaric acid because it lacks a plane of symmetry.

Therefore, the correct structure of the D-aldotetrose is given in option (C).

Answer: A D-aldotetrose on oxidation with concentrated HNO_3 resulted in optically inactive dicarboxylic acid. The structure of
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