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JEE Main 202624 JanuaryMorning Shift
Exam
JEE Main
Year
2026
Date
24 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Biomolecules

JEE Main 2026 · 24 January · Morning Shift · Chemistry · Biomolecules

A student is given one compound among the following compounds that...

A student is given one compound among the following compounds that gives positive test with Tollen's reagent.
A student is given one compound among the following compounds that gives positive test with Tollen's reagent. The
The compound is :

Options

  1. AD
  2. BA
  3. CB
  4. DC

Correct answer

D. C

Step-by-step solution

Tollen's reagent is a mild oxidizing agent that gives a positive test (silver mirror) with aldehydes and α\alpha-hydroxy ketones.
In cyclic structures, hemiacetals are in equilibrium with their open-chain hydroxy-aldehyde forms in aqueous solution, whereas acetals and ethers are stable and do not open up.
Compound A is a cyclic acetal (specifically a methyl glycoside type structure). It is stable and does not show Tollen's test.
Compound B is a cyclic ether with a methoxy group at a non-anomeric position. It is stable.
Compound C is a cyclic hemiacetal. The carbon attached to both the ring oxygen and the −OH-OH group is the hemiacetal carbon. In solution, it exists in equilibrium with its open-chain form which contains an aldehyde group: HO−CH2−CH2−CH2−CHOHO-CH_2-CH_2-CH_2-CHO. Therefore, it gives a positive Tollen's test.
Compound D is a cyclic ether with an alcohol group at a non-anomeric position. It does not have a hemiacetal linkage and will not give a positive Tollen's test.
Thus, the correct compound is C.
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