JEE Main 202624 JanuaryMorning Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 24 January
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Biomolecules
JEE Main 2026 · 24 January · Morning Shift · Chemistry · Biomolecules
A student is given one compound among the following compounds that...
A student is given one compound among the following compounds that gives positive test with Tollen's reagent.

The compound is :
The compound is :
Options
- AD
- BA
- CB
- DC
Correct answer
D. C
Step-by-step solution
Tollen's reagent is a mild oxidizing agent that gives a positive test (silver mirror) with aldehydes and -hydroxy ketones.
In cyclic structures, hemiacetals are in equilibrium with their open-chain hydroxy-aldehyde forms in aqueous solution, whereas acetals and ethers are stable and do not open up.
Compound A is a cyclic acetal (specifically a methyl glycoside type structure). It is stable and does not show Tollen's test.
Compound B is a cyclic ether with a methoxy group at a non-anomeric position. It is stable.
Compound C is a cyclic hemiacetal. The carbon attached to both the ring oxygen and the group is the hemiacetal carbon. In solution, it exists in equilibrium with its open-chain form which contains an aldehyde group: . Therefore, it gives a positive Tollen's test.
Compound D is a cyclic ether with an alcohol group at a non-anomeric position. It does not have a hemiacetal linkage and will not give a positive Tollen's test.
Thus, the correct compound is C.
In cyclic structures, hemiacetals are in equilibrium with their open-chain hydroxy-aldehyde forms in aqueous solution, whereas acetals and ethers are stable and do not open up.
Compound A is a cyclic acetal (specifically a methyl glycoside type structure). It is stable and does not show Tollen's test.
Compound B is a cyclic ether with a methoxy group at a non-anomeric position. It is stable.
Compound C is a cyclic hemiacetal. The carbon attached to both the ring oxygen and the group is the hemiacetal carbon. In solution, it exists in equilibrium with its open-chain form which contains an aldehyde group: . Therefore, it gives a positive Tollen's test.
Compound D is a cyclic ether with an alcohol group at a non-anomeric position. It does not have a hemiacetal linkage and will not give a positive Tollen's test.
Thus, the correct compound is C.