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JEE Main 202431 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
31 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Biomolecules

JEE Main 2024 · 31 January · Morning Shift · Chemistry · Biomolecules

Match List I with List II List-I List-II A. Glucose/ NaHCO _ 3 / ∆...

Match List I with List II

  List-I   List-II
A. Glucose/NaHCO3/∆{NaHCO}_{3} / ∆ I. Gluconic acid
B. Glucose/HNO3{HNO}_{3} II. No reaction
C. Glucose/HI/∆HI / ∆ III. nn-hexane
D. Glucose/Bromine water IV. Saccharic acid

Choose the correct answer from the options given below:

Options

  1. AA-IV, B-I, C-III, D-II
  2. BA-II, B-IV, C-III, D-I
  3. CA-III, B-II, C-I, D-IV
  4. DA-I, B-IV, C-III, D-II

Correct answer

B. A-II, B-IV, C-III, D-I

Step-by-step solution

Glucose\mathop{\to}_{∆}^{{NaHCO}_{3}}noreaction</p><p>Glucose→∆HNO3saccharicacid</p><p>Glucose\mathop{\to}_{∆}^{{HNO}_{3}}saccharicacid

Glucose, on oxidation with nitric acid, gives saccharic acid.

Glucose\mathop{\to}_{∆}^{HI}n - hexane</p><p>Glucose,onprolongedheatingwithhotHI,givesn−Hexane.</p><p>Glucose→∆Br2Gluconicacid</p><p>Glucose, on prolonged heating with hot HI, gives n-Hexane.</p><p>Glucose\mathop{\to}_{∆}^{{Br}_{2}}Gluconicacid

Glucose reacts with bromine water to form gluconic acid.

 Bromine water is a mild oxidising agent which selectively oxidizes aldehyde to carboxylic acid only. It doesn’t oxidise alcohol or ketone.

Hence option B is the answer.

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