JEE Main 20265 AprilEvening Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 5 April
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Carboxylic Acid Derivatives
JEE Main 2026 · 5 April · Evening Shift · Chemistry · Carboxylic Acid Derivatives
Complete the following reaction sequence and give the name of major...
Complete the following reaction sequence and give the name of major product 'P'.
Options
- A2-Chloropropanoic acid
- B3-Chloropropanoic acid
- C1-Chloropropane
- D2-Chloropropane
Correct answer
A. 2-Chloropropanoic acid
Step-by-step solution
Step 1: Hydrolysis of the nitrile.
Propanenitrile on basic hydrolysis followed by acidic workup gives propanoic acid:
Step 2: HellVolhardZelinsky (HVZ) reaction.
Propanoic acid has an -carbon bearing two -hydrogens. In the HVZ reaction, in the presence of red phosphorus selectively replaces one -hydrogen by chlorine, giving the -chloro acid after aqueous workup:
Hence, the major product is -chloropropanoic acid, which corresponds to option .
Propanenitrile on basic hydrolysis followed by acidic workup gives propanoic acid:
Step 2: HellVolhardZelinsky (HVZ) reaction.
Propanoic acid has an -carbon bearing two -hydrogens. In the HVZ reaction, in the presence of red phosphorus selectively replaces one -hydrogen by chlorine, giving the -chloro acid after aqueous workup:
Hence, the major product is -chloropropanoic acid, which corresponds to option .