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JEE Main 20264 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

JEE Main 2026 · 4 April · Evening Shift · Chemistry · Carboxylic Acid Derivatives

The descending order of acidity among the following compounds is:...

The descending order of acidity among the following compounds is:
A. Phenol
B. 44-nitrophenol
C. 44-methoxyphenol
D. 44-nitrobenzoic acid
E. Benzoic acid
The descending order of acidity among the following compounds is: A. Phenol B. 4 -nitrophenol C. 4 -methoxyphenol D. 4
Choose the correct answer from the options given below:

Options

  1. AB>D>E>A>CB>D>E>A>C
  2. BD>B>E>A>CD>B>E>A>C
  3. CC>A>B>D>EC>A>B>D>E
  4. DD>E>B>A>CD>E>B>A>C

Correct answer

D. D>E>B>A>CD>E>B>A>C

Step-by-step solution

Carboxylic acids are stronger acids than phenols because the carboxylate anion is stabilized by equivalent resonance structures. Thus, D and E are more acidic than A, B, and C.

For the carboxylic acids, the −NO2-NO_2 group in D is an electron-withdrawing group (−I,−R-I, -R), which stabilizes the conjugate base, making D more acidic than E.

For the phenols, electron-withdrawing groups increase acidity while electron-donating groups decrease it. The −NO2-NO_2 group in B is electron-withdrawing, making it more acidic than A. The −OCH3-OCH_3 group in C is electron-donating (+R>−I+R > -I), making it less acidic than A. Thus, the order for phenols is B >> A >> C.

Combining these, the overall descending order of acidity is D >> E >> B >> A >> C.

Answer: D>E>B>A>CD>E>B>A>C
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