JEE Main 20264 AprilEvening Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 4 April
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Carboxylic Acid Derivatives
JEE Main 2026 · 4 April · Evening Shift · Chemistry · Carboxylic Acid Derivatives
The descending order of acidity among the following compounds is:...
The descending order of acidity among the following compounds is:
A. Phenol
B. -nitrophenol
C. -methoxyphenol
D. -nitrobenzoic acid
E. Benzoic acid

Choose the correct answer from the options given below:
A. Phenol
B. -nitrophenol
C. -methoxyphenol
D. -nitrobenzoic acid
E. Benzoic acid
Choose the correct answer from the options given below:
Options
- A
- B
- C
- D
Correct answer
D.
Step-by-step solution
Carboxylic acids are stronger acids than phenols because the carboxylate anion is stabilized by equivalent resonance structures. Thus, D and E are more acidic than A, B, and C.
For the carboxylic acids, the group in D is an electron-withdrawing group (), which stabilizes the conjugate base, making D more acidic than E.
For the phenols, electron-withdrawing groups increase acidity while electron-donating groups decrease it. The group in B is electron-withdrawing, making it more acidic than A. The group in C is electron-donating (), making it less acidic than A. Thus, the order for phenols is B A C.
Combining these, the overall descending order of acidity is D E B A C.
Answer:
For the carboxylic acids, the group in D is an electron-withdrawing group (), which stabilizes the conjugate base, making D more acidic than E.
For the phenols, electron-withdrawing groups increase acidity while electron-donating groups decrease it. The group in B is electron-withdrawing, making it more acidic than A. The group in C is electron-donating (), making it less acidic than A. Thus, the order for phenols is B A C.
Combining these, the overall descending order of acidity is D E B A C.
Answer: