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JEE Main 202331 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
31 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Equilibrium

JEE Main 2023 · 31 January · Morning Shift · Chemistry · Chemical Equilibrium

For reaction: SO _ 2 ( g ) + (1)/(2) O _ 2 ( g ) ⇌ SO _ 3 ( g ) K _...

For reaction: SO2(g)+12O2(g)⇌SO3(g){SO}_{2} ( g ) + \dfrac{1}{2}{O}_{2} ( g ) ⇌ {SO}_{3} ( g ) KP=2×1012{K}_{P} = 2 \times {10}^{12} at 27°C27 ° C and 1atm1atm pressure. The Kc{K}_{c} for the same reaction is ×1013.(\times {10}^{13} . ( Nearest integer)
(Given R=0.082LatmK−1mol−1R = 0 . 082Latm{K}^{- 1}{mol}^{- 1} )

Correct answer

0

Step-by-step solution

For reaction: SO2(g)+12O2(g)⇌SO3(g){SO}_{2 ( g )} + \dfrac{1}{2}{O}_{2 ( g )} ⇌ {SO}_{3 ( g )}

Kp=2×1012{K}_{p} = 2 \times {10}^{12} at 300K300K and 1atm1atm pressure.

The relation between equilibrium constant in terms of pressures Kp{K}_{p} and equilibrium constant in terms of concentration Kc{K}_{c} is

Kp=Kc×(RT)∆ng{K}_{p} = {K}_{c} \times ( RT{)}^{∆ ng}

⇒2×1012=Kc×(0.082×300)−12⇒ 2 \times {10}^{12} = {K}_{c} \times ( 0 . 082 \times 300{)}^{- \dfrac{1}{2}}

⇒KC=9.92×1012⇒ {K}_{C} = 9 . 92 \times {10}^{12}

⇒KC=0.992×1013⇒ {K}_{C} = 0 . 992 \times {10}^{13}

So, answer is 1.

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