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JEE Main 20231 FebruaryMorning Shift
Exam
JEE Main
Year
2023
Date
1 February
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Equilibrium

JEE Main 2023 · 1 February · Morning Shift · Chemistry · Chemical Equilibrium

(i) X ( g ) ⇌ Y ( g ) + Z ( g ) K _ p1 = 3 (ii) A ( g ) ⇌ 2B ( g )...

(i) X(g)⇌Y(g)+Z(g)Kp1=3X ( g ) ⇌ Y ( g ) + Z ( g ) {K}_{p1} = 3

(ii) A(g)⇌2B(g)Kp2=1A ( g ) ⇌ 2B ( g ) {K}_{p2} = 1

If the degree of dissociation and initial concentration of both the reactants X(g)andA(g)X ( g ) and A ( g ) are equal, then the ratio of the total pressure at equilibrium (p1p2)\left(\dfrac{{p}_{1}}{{p}_{2}}\right) is equal to x:1x: 1. The value of xx is (Nearest integer)

Correct answer

0

Step-by-step solution

X(g)⇌Y(g)+Z(g)Kp1=3X ( g ) ⇌ Y ( g ) + Z ( g ) {K}_{{p}_{1}} = 3

nn Initial concentration

n−\alphan\alphan\alphann - \alphan\alphan\alphan at equilibrium
Let total pressure be p1{p}_{1}

Using dalton's law of partial pressures and equation for equilibrium constant:
∴Kp1=(α1+α×p1)21−α1+αp1∴ {K}_{{p}_{1}} = \dfrac{{\left(\dfrac{\alpha}{1 + \alpha} \times {p}_{1}\right)}^{2}}{\dfrac{1 - \alpha}{1 + \alpha}{p}_{1}}

⇒3=α2×p11−α2⇒ 3 = \dfrac{{\alpha}^{2} \times {p}_{1}}{1 - {\alpha}^{2}} ....(X)

A(g)⇌2B(g)kp2=1A ( g ) ⇌ 2B ( g ) {k}_{{p}_{2}} = 1

nn Initial mole

x−αn2αnx - \alpha n2\alpha n at equilibrium
Let total pressure be p2{p}_{2}
Using dalton's law of partial pressures and equation for equilibrium constant

∴kp2=(2α1+α×p2)21−α1+α×p2∴ {k}_{{p}_{2}} = \dfrac{{\left(\dfrac{2\alpha}{1 + \alpha} \times {p}_{2}\right)}^{2}}{\dfrac{1 - \alpha}{1 + \alpha} \times {p}_{2}}

⇒1=4α2×p21−α2⇒ 1 = \dfrac{4{\alpha}^{2} \times {p}_{2}}{1 - {\alpha}^{2}} ....(Y)
Thus, dividing equation (X) by equation(Y)

⇒kp1kp2=p14p2⇒ \dfrac{{k}_{{p}_{1}}}{{k}_{{p}_{2}}} = \dfrac{{p}_{1}}{4{p}_{2}}

⇒31=p14p2⇒ \dfrac{3}{1} = \dfrac{{p}_{1}}{4{p}_{2}}

∴p1p2=12∴ \dfrac{{p}_{1}}{{p}_{2}} = 12

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