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JEE Main 202227 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
27 June
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Equilibrium

JEE Main 2022 · 27 June · Morning Shift · Chemistry · Chemical Equilibrium

2NOCl(g) ⇌ 2NO(g) + Cl _ 2 (g) In an experiment, 2 . 0 moles of...

2NOCl(g)⇌2NO(g)+Cl2(g)2NOCl\left(g\right) ⇌ 2NO\left(g\right) + {Cl}_{2}\left(g\right)

In an experiment, 2.02 . 0 moles of NOClNOCl was placed in a one-litre flask and the concentration of NONO after equilibrium established, was found to be 0.4mol/L0 . 4mol / L. The equilibrium constant at 30°C30 ° C is_____×10−4\times {10}^{- 4}.

Correct answer

0

Step-by-step solution

2NOCl(g)⇌2NO(g)+Cl2(g)2NOCl\left(g\right) ⇌ 2NO\left(g\right) + {Cl}_{2}\left(g\right)

{t=02M\begin{cases}t = 0 & 2M\end{cases}

{t=teq(2−x)MxMx2M\begin{cases}t = {t}_{eq}\left(2 - x\right)M & xM & \dfrac{x}{2}M\end{cases}

∵x=0.4M∵ x = 0 . 4M

∴[NOCl]eq=1.6M∴ {\left[NOCl\right]}_{eq} = 1 . 6M

[NO]eq=0.4M{\left[NO\right]}_{eq} = 0 . 4M

[Cl2]eq=0.2M{\left[{Cl}_{2}\right]}_{eq} = 0 . 2M

⇒Kc=[NO]2[Cl2][NOCl]2=[0.4]2[0.2][1.6]2⇒ {K}_{c} = \dfrac{{\left[NO\right]}^{2}\left[{Cl}_{2}\right]}{{\left[NOCl\right]}^{2}} = \dfrac{{\left[0 . 4\right]}^{2}\left[0 . 2\right]}{{\left[1 . 6\right]}^{2}}

Kc=322.56×10−3{K}_{c} = \dfrac{32}{2 . 56} \times {10}^{- 3}

Kc=12.5×10−3{K}_{c} = 12 . 5 \times {10}^{- 3}

Kc=125×10−4{K}_{c} = 125 \times {10}^{- 4}

Integer answer is 125125

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