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JEE Main 202127 JulyMorning Shift
Exam
JEE Main
Year
2021
Date
27 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Equilibrium

JEE Main 2021 · 27 July · Morning Shift · Chemistry · Chemical Equilibrium

PCl _ 5 ⇌ PCl _ 3 + Cl _ 2 K _ c = 1 . 844 3 . 0 moles of PCl _ 5...

PCl5⇌PCl3+Cl2Kc=1.844{PCl}_{5} ⇌ {PCl}_{3} + {Cl}_{2}{K}_{c} = 1 . 844
3.03 . 0 moles of PCl5{PCl}_{5} is introduced in a 1L1L closed reaction vessel at 380K.380K . The number of moles of PCl5{PCl}_{5} at equilibrium is —×10−3— \times {10}^{- 3}
(Round off to the Nearest Integer)

Correct answer

0

Step-by-step solution

PCl5(g)⇌PCl3(g)+Cl2(g)Kc=1.844t=0300t=teq3−xxx{PCl}_{5 ( g )} ⇌ {PCl}_{3 ( g )} + {Cl}_{2 ( g )}{K}_{c} = 1 . 844t = 0300t = {t}_{eq}3 - xxx


⇒[PCl3][Cl2][PCl5]=x23−x=1.844⇒ \dfrac{\left[{PCl}_{3}\right]\left[{Cl}_{2}\right]}{\left[{PCl}_{5}\right]} = \dfrac{{x}^{2}}{3 - x} = 1 . 844
⇒x2+1.844−5.532=0⇒ {x}^{2} + 1 . 844 - 5 . 532 = 0
⇒x=−1.844+(1.844)2+4×5.5322⇒ x = \dfrac{- 1 . 844 + \sqrt{( 1 . 844{)}^{2} + 4 \times 5 . 532}}{2}
≡1.60≡ 1 . 60
⇒⇒ Moles of PCl5=3−1.60=1.40{PCl}_{5} = 3 - 1 . 60 = 1 . 40

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