JEE Main 202621 JanuaryEvening Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 21 January
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Electrochemistry
JEE Main 2026 · 21 January · Evening Shift · Chemistry · Electrochemistry
MX is a sparingly soluble salt that follows the given solubility...
MX is a sparingly soluble salt that follows the given solubility equilibrium at 298 K.
If the standard reduction potential for is \left(\mathrm{E}_{\mathrm{M}^{+} / \mathrm{M}}^{\ominus}\right)=0.79 \mathrm{~V}\mathrm{E}_{\mathrm{X}^{-} / \mathrm{MX}(\mathrm{s}) / \mathrm{M}}^{\ominus} is mV. (nearest integer)
[Given : ]
If the standard reduction potential for is \left(\mathrm{E}_{\mathrm{M}^{+} / \mathrm{M}}^{\ominus}\right)=0.79 \mathrm{~V}\mathrm{E}_{\mathrm{X}^{-} / \mathrm{MX}(\mathrm{s}) / \mathrm{M}}^{\ominus} is mV. (nearest integer)
[Given : ]
Correct answer
0
Step-by-step solution
The standard reduction potential for a metal/metal insoluble salt electrode is related to the standard reduction potential of the metal ion and the solubility product of the salt.
The half-cell reaction for the electrode is: .
This can be viewed as a combination of two processes:
1. with equilibrium constant
2. with
The relation between the standard potentials is given by:
Given and :
To convert the value into mV:
The half-cell reaction for the electrode is: .
This can be viewed as a combination of two processes:
1. with equilibrium constant
2. with
The relation between the standard potentials is given by:
Given and :
To convert the value into mV: