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JEE Main 202429 JanuaryEvening Shift
Exam
JEE Main
Year
2024
Date
29 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Electrochemistry

JEE Main 2024 · 29 January · Evening Shift · Chemistry · Electrochemistry

A constant current was passed through a solution of AuCl _ 4 ^ -...

A constant current was passed through a solution of AuCl4−{AuCl}_{4}^{-} ion between gold electrodes. After a period of 10.010 . 0 minutes, the increase in mass of cathode was 1.314g1 . 314g. The total charge passed through the solution is ___×10−2F\times {10}^{- 2}F. (Given atomic mass of Au=197)Au = 197 )

Correct answer

0

Step-by-step solution

The half-cell reaction is,

Au3++3e−→Au{Au}^{3 +} + 3{e}^{-} \to Au

Given W = 1.314g1 . 314g

Atomic mass of Au=197Au = 197

When one Faraday of charge is passed through a circuit, then one equivalent of charge is deposited at the respective electrode.

WE=charge1F\dfrac{W}{E} = \dfrac{charge}{1F}

1.3141973=Q1F\dfrac{1 . 314}{\dfrac{197}{3}} = \dfrac{Q}{1F}

Q=2×10−2FQ = 2 \times {10}^{- 2}F

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