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JEE Main 202229 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
29 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Electrochemistry

JEE Main 2022 · 29 July · Morning Shift · Chemistry · Electrochemistry

Resistance of a conductivity cell (cell constant 129 m ^ - 1 )...

Resistance of a conductivity cell (cell constant 129m−1129{m}^{- 1}) filled with 74.5ppm74 . 5ppm solution of KClKCl is 100Ω100Ω (labelled as solution 11). When the same cell is filled with KClKCl solution of 149ppm149ppm, the resistance is 50Ω50Ω (labelled as solution 22). The ratio of molar conductivity of solution 11 and solution 22 is i.e. ∧1∧2=x×10−3\dfrac{{∧}_{1}}{{∧}_{2}} = x \times {10}^{- 3}. The value of xx is____Given, molar mass of KClKCl is 74.5gmol−174 . 5g{mol}^{- 1})

Correct answer

0

Step-by-step solution

Given lA=129m−1\dfrac{l}{A} = 129{m}^{- 1}

KClKCl solution 11:

74.5ppm,R1=100Ω74 . 5ppm, {R}_{1} = 100Ω

KClKCl solution 22:

149ppm,R2=50Ω149ppm, {R}_{2} = 50Ω

Here, ppm1ppm2=M1M2\dfrac{{ppm}_{1}}{{ppm}_{2}} = \dfrac{{M}_{1}}{{M}_{2}}

and κ=1RG∗whereG∗=cellconstantκ = \dfrac{1}{R}G * whereG * = cellconstant

Since value of cell constant is same in both the cases.

k1k2=R2R1\dfrac{{k}_{1}}{{k}_{2}} = \dfrac{{R}_{2}}{{R}_{1}}

∧1∧2=k1×1000M1k2×1000M2\dfrac{{∧}_{1}}{{∧}_{2}} = \dfrac{{k}_{1} \times \dfrac{1000}{{M}_{1}}}{{k}_{2} \times \dfrac{1000}{{M}_{2}}}

=K1K2×M2M1=R2R1×M2M1= \dfrac{{K}_{1}}{{K}_{2}} \times \dfrac{{M}_{2}}{{M}_{1}} = \dfrac{{R}_{2}}{{R}_{1}} \times \dfrac{{M}_{2}}{{M}_{1}}

=50100×14974.5=1= \dfrac{50}{100} \times \dfrac{149}{74 . 5} = 1

=∧1∧2=1,000×10−3= \dfrac{{∧}_{1}}{{∧}_{2}} = 1, 000 \times {10}^{- 3}

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