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JEE Main 202229 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
29 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Electrochemistry

JEE Main 2022 · 29 June · Evening Shift · Chemistry · Electrochemistry

The cell potential for the given cell at 298KPt | H _ 2 (g, 1bar)||...

The cell potential for the given cell at 298KPt298KPt\left|{H}_{2}\left(g, 1bar\right)\right|\left|{H}^{+}\left(aq\right) ‖ {Cu}^{2 +}\left(aq\right)\right|Cu\left(s\right)isis0 . 31V.The. ThepHoftheacidicsolutionisfoundtobeof the acidic solution is found to be3,whereastheconcentrationof, whereas the concentration of{Cu}^{2 +} is 10xM{10}^{x}M. The value of xx is _________.

(Given: ECu2+/CuΘ=0.34V{E}_{{Cu}^{2 +} / Cu}^{Θ} = 0 . 34V and 2.303RTF=0.06V\dfrac{2 . 303RT}{F} = 0 . 06V)

Correct answer

0

Step-by-step solution

{H}_{2}(g)\left(g\right) + {Cu}^{2 +}\left(aq .\right)→2H+(aq.)\to 2{H}^{+}\left(aq .\right) + Cu\left(s\right)</p><p>Applyingnernstequation</p><p></p><p>Applying nernst equation</p><p>{E}_{cell} = {E}_{cell}^{0} - \dfrac{0 . 06}{n}log\dfrac{\left[products\right]}{\left[Reactants\right]}</p><p></p><p>{E}_{cell} = Cellpotential = 0 . 31V{E}_{cell}^{0} = 0 . 34{p}^{H} = 3, Hence, \left[{H}^{+}\right] = {10}^{- 3}</p><p></p><p>0 . 31 = 0 . 34 - \dfrac{0 . 06}{2}log\dfrac{{\left[{H}^{+}\right]}^{2}}{\left[{Cu}^{2 +}\right]}</p><p>[Cu2+]=10−7M</p><p>\left[{Cu}^{2 +}\right] = {10}^{- 7}M

x=7x = 7

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