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JEE Main 202227 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
27 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Electrochemistry

JEE Main 2022 · 27 June · Evening Shift · Chemistry · Electrochemistry

For the reaction taking place in the cell: Pt(s) H _ 2 (g) H ^ +...

For the reaction taking place in the cell:

Pt\left(s\right){H}_{2}\left(g\right){H}^{+}\left(aq\right)\left||{Ag}^{+}\left(aq\right)\left|Ag\left(s\right)\right\right)</p><p>{E}_{cell}^{°} = + 0 . 5332V .</p><p>Thevalueof</p><p>The value of{\Delta}_{f}{G}^{⊖} is kJmol−1{kJmol}^{- 1}. (in nearest integer)

Correct answer

0

Step-by-step solution

Anode⇒12H2(g)⟶H+(aq)+e−Cathode⇒Ag++e−⟶Ag(s)\begin{array}{ll}Anode ⇒ \dfrac{1}{2}{H}_{2}\left(g\right) ⟶ {H}^{+}\left(aq\right) + {e}^{-} \\ Cathode ⇒ {Ag}^{+} + {e}^{-} ⟶ Ag ( s )\end{array}\dfrac{1}{2}{H}_{2}\left(g\right) + {Ag}^{+}\left(aq\right)\overset{n = 1}{⟶}{H}^{+}\left(aq\right) + Ag\left(s\right)</p><p>RelationbetweenGibbsFreeEnergyandEMFofaCellisgivenby</p><p></p><p>Relation between Gibbs Free Energy and EMF of a Cell is given by</p><p>\Delta G ° = - {nFE}_{cell}^{°} = - 1 \times 96500 \times 0 . 5332 = 51453 . 8J{mol}^{- 1} = 51 . 4538kJ{mol}^{- 1}$

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