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JEE Main 201912 JanuaryEvening Shift
Exam
JEE Main
Year
2019
Date
12 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Electrochemistry

JEE Main 2019 · 12 January · Evening Shift · Chemistry · Electrochemistry

∧ _ m ^ o for NaCl, HCl and NaA are 126.4, 425.9 and 100 .5 S cm ^...

∧mo{∧}_{m}^{o} for NaCl,HClNaCl, HCl and NaANaA are 126.4,425.9126.4, 425.9 and 100.5Scm2mol−1100 .5 S{cm}^{2}{mol}^{- 1} respectively. If the conductivity of 0.001MHA0 .001 MHA is 5×10−5Scm−15 \times {10}^{- 5}S{cm}^{- 1}, degree of dissociation of HAHA is

Options

  1. A0.1250.125
  2. B0.750.75
  3. C0.250.25
  4. D0.500.50

Correct answer

A. 0.1250.125

Step-by-step solution

Kohlrausch's law states that the equivalent conductivity of an electrolyte at infinite dilution is equal to the sum of the conductances of the anions and cations.

λmo(HA)=λmo(HCl)+λmo(NaA)−λo(NaCl){\lambda}_{m}^{o}\left(HA\right) = {\lambda}_{m}^{o}\left(HCl\right) + {\lambda}_{m}^{o}\left(NaA\right) - {\lambda}^{o}\left(NaCl\right)

=425.9+100.5−126.4= 425.9 + 100.5 - 126.4

=400= 400

λmo=K×1000M=5×10−5×10310−3=50{\lambda}_{m}^{o} = \dfrac{K \times 1000}{M} = \dfrac{5 \times {10}^{- 5} \times {10}^{3}}{{10}^{- 3}} = 50

α=50400=0.125\alpha = \dfrac{50}{400} = 0 .125

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