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JEE Main 201910 JanuaryMorning Shift
Exam
JEE Main
Year
2019
Date
10 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Electrochemistry

JEE Main 2019 · 10 January · Morning Shift · Chemistry · Electrochemistry

Consider the following reduction processes: Zn ^ 2 + + 2 e ^ - → Zn...

Consider the following reduction processes:

Zn2++2e−→Zn(s);Eo=−0.76V{Zn}^{2 +} + 2{e}^{-} \to Zn ( s ) ; {E}^{o} = - 0 .76 V

Ca2++2e−→Ca(s);Eo=−2.87V{Ca}^{2 +} + 2{e}^{-} \to Ca ( s ) ; {E}^{o} = - 2 .87 V

Mg2++2e−→Mg(s);Eo=−2.36V{Mg}^{2 +} + 2{e}^{-} \to Mg ( s ) ; {E}^{o} = - 2 .36 V

Ni2++2e−→Ni(s);Eo=−0.25V{Ni}^{2 +} + 2{e}^{-} \to Ni ( s ) ; {E}^{o} = - 0 .25 V

The reducing power of the metals increases in the order:

Options

  1. ACa<Mg<Zn<NiCa < Mg < Zn < Ni
  2. BZn<Mg<Ni<CaZn < Mg < Ni < Ca
  3. CNi<Zn<Mg<CaNi < Zn < Mg < Ca
  4. DCa<Zn<Ni<MgCa < Zn < Ni < Mg

Correct answer

C. Ni<Zn<Mg<CaNi < Zn < Mg < Ca

Step-by-step solution

Lower the standard reduction potential more will be the reducing power i.e gets self oxidised.

Therefore the correct order is:

Ni<Zn<Mg<CaNi < Zn < Mg < Ca
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