JEE Main2015ChemistryElectrochemistryActual
A variable, the opposite external potential ( E ext ) is applied to the cell Z n | Z n 2 + 1 M ∥ C u 2 + 1 M | C u , of potential 1 . 1 V . When E e x t < 1.1 V and E e x t > 1.1 V , respectively electrons flow from
Options
- Aanode to cathode in both the cases.
- Banode to cathode and cathode to anode.
- Ccathode to anode and anode to cathode.
- Dcathode to anode in both cases.
Correct answer
B. anode to cathode and cathode to anode.
Step-by-step solution
For a Daniel cell, E c e l l = 0.34 - ( - 0.76 ) = 1.10   V . When E e x t < 1.10   V , electrons flow from anode to cathode in the external circuit. When E e x t > 1.10   V , electrons flow from cathode to anode in the external circuit (reverse reaction).