JEE Main2014ChemistryElectrochemistryActual
The standard electrode potentials E M + / M o of four metals A,   B,   C and D are − 1 .2   V, 0 .6   V , 0 .85   V and − 0 .76   V , respectively. The sequence of deposition of metals on applying potential is
Options
- AB   >   D   >   C   >   A
- BA   >   C   >   B   >   D
- CC   >   B   >   D   >   A
- DD   >   A   >   B   >   C
Correct answer
C. C   >   B   >   D   >   A
Step-by-step solution
In complete cation electrolysis at cathode, the species having higher reduction potential is preferably reduced at cathode E C ∘ > E B ∘ > E D ∘ > E A ∘ Hence, C   >   B   >   D   >   A will be the preference of deposition of these metals on competing.