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99 Percentile Qs Bank for JEE MainChemistryAldehydes and Ketones

The organic compound is taken in a clean test tube and some ammonical silver nitrate solution is added to it. The mixture is then warmed. The formation of a shining silver mirror on the sides of the test tube takes place. This indicates the presence of

Options

  1. ACarboxylic acid group in the organic compound
  2. BKetone group in the organic compound
  3. CAldehyde group in the organic compound
  4. DEster group in the organic compound

Correct answer

C. Aldehyde group in the organic compound

Step-by-step solution

Tollens' reagent is a chemical reagent most commonly used to determine whether a known carbonyl-containing compound is an aldehyde or a ketone. It is usually ammonical silver nitrate, but can also be other mixtures, as long as aqueous diamminesilver(I) complex is present. It was named after its discoverer, the German chemist Bernhard Tollens. A positive test with Tollens' reagent results in elemental silver precipitating out of solution, occasionally onto the inner surface of the reaction vessel, producing

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