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JEE Main 202329 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
29 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Hydrocarbons

JEE Main 2023 · 29 January · Morning Shift · Chemistry · Hydrocarbons

17mg of a hydrocarbon (M.F. C _ 10 H _ 16 ) takes up 8 . 40mL of...

17mg17mg of a hydrocarbon (M.F. C10H16{C}_{10}{H}_{16}) takes up 8.40mL8 . 40mL of the H2{H}_{2} gas measured at 0°C0 ° C and 760mm760mm of HgHg. Ozonolysis of the same hydrocarbon yields

CH3−C∣∣O−CH3,H−C∣∣O−H,H−C∣∣O−CH2−CH2−C∣∣O−C∣∣O−H{CH}_{3} - \mathop{C}_{\mathop{| |}_{O}} - {CH}_{3}, H - \mathop{C}_{\mathop{| |}_{O}} - H, H - \mathop{C}_{\mathop{| |}_{O}} - {CH}_{2} - {CH}_{2} - \mathop{C}_{\mathop{| |}_{O}} - \mathop{C}_{\mathop{| |}_{O}} - H

The number of double bond/s present in the hydrocarbon is

Correct answer

3

Step-by-step solution

From the given information:
Moles of hydrocarbon =17×10−3136=1.25×10−4= \dfrac{17 \times {10}^{- 3}}{136} = 1 . 25 \times {10}^{- 4} Mole of H2{H}_{2} gas

⇒1×8.401000=n×0.0821×273⇒ 1 \times \dfrac{8 . 40}{1000} = n \times 0 . 0821 \times 273

⇒n=3.75×10−4⇒ n = 3 . 75 \times {10}^{- 4}

Thus, moles of hydrogen used to hydrogenate double bonds:

=3.75×10−41.25×10−4=3= \dfrac{3 . 75 \times {10}^{- 4}}{1 . 25 \times {10}^{- 4}} = 3

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