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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Bohr's Model and Physics of the Atom

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Bohr's Model and Physics of the Atom

A hot gas emits radiation exclusively at wavelengths of 46.0 nm ,...

A hot gas emits radiation exclusively at wavelengths of 46.0 nm46.0 \text{ nm}, 82.8 nm82.8 \text{ nm}, and 103.5 nm103.5 \text{ nm}. Assume the atoms possess only two excited states, and the energy difference between consecutive levels decreases with increasing energy. If the energy of the highest state is taken as zero, determine the energies of the ground state and the first excited state.

Options

  1. A−15 eV-15 \text{ eV} and −12 eV-12 \text{ eV}
  2. B−27 eV-27 \text{ eV} and −12 eV-12 \text{ eV}
  3. C−27 eV-27 \text{ eV} and −15 eV-15 \text{ eV}
  4. D−12 eV-12 \text{ eV} and −27 eV-27 \text{ eV}

Correct answer

B. −27 eV-27 \text{ eV} and −12 eV-12 \text{ eV}

Step-by-step solution

The energies of the emitted photons are calculated using E=hcλE = \dfrac{hc}{\lambda}, taking hc=1242 eV nmhc = 1242 \text{ eV nm}.

Ea=124246.0=27 eVE_a = \dfrac{1242}{46.0} = 27 \text{ eV}

Eb=124282.8=15 eVE_b = \dfrac{1242}{82.8} = 15 \text{ eV}

Ec=1242103.5=12 eVE_c = \dfrac{1242}{103.5} = 12 \text{ eV}

The gas has three energy levels: ground state E1E_1, first excited state E2E_2, and second excited state E3E_3. The highest energy transition corresponds to E3−E1=27 eVE_3 - E_1 = 27 \text{ eV}.

The other two transitions are E2−E1E_2 - E_1 and E3−E2E_3 - E_2, which must be 15 eV15 \text{ eV} and 12 eV12 \text{ eV}.

It is given that the energy difference between consecutive levels decreases with increasing energy, which implies E2−E1>E3−E2E_2 - E_1 > E_3 - E_2.

Therefore, E2−E1=15 eVE_2 - E_1 = 15 \text{ eV} and E3−E2=12 eVE_3 - E_2 = 12 \text{ eV}.

Taking the energy of the highest state as zero (E3=0E_3 = 0), we get:

0−E2=12⇒E2=−12 eV0 - E_2 = 12 \Rightarrow E_2 = -12 \text{ eV}

−12−E1=15⇒E1=−27 eV-12 - E_1 = 15 \Rightarrow E_1 = -27 \text{ eV}

The energies of the ground state and the first excited state are −27 eV-27 \text{ eV} and −12 eV-12 \text{ eV} respectively.
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