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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Laws of Thermodynamics

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Laws of Thermodynamics

Determine the increase in the internal energy of 10 g of water as...

Determine the increase in the internal energy of 10 g10 \text{ g} of water as it is heated from 0^{}^{{}^{\circ}}\text{C} to 100^{}^{{}^{\circ}}\text{C} and subsequently transformed into steam at 100 kPa100 \text{ kPa}. The density of the steam is 0.6 kg m−30.6 \text{ kg m}^{-3}. Assume the specific heat capacity of water is 4200 \text{ J kg}^{-1} ^{}^{{}^{\circ}}\textC^{-1} and the latent heat of vaporization of water is 2.25×106 J kg−12.25 \times 10^6 \text{ J kg}^{-1}.

Options

  1. A2.25×104 J2.25 \times 10^4 \text{ J}
  2. B2.08×104 J2.08 \times 10^4 \text{ J}
  3. C2.50×104 J2.50 \times 10^4 \text{ J}
  4. D2.67×104 J2.67 \times 10^4 \text{ J}

Correct answer

C. 2.50×104 J2.50 \times 10^4 \text{ J}

Step-by-step solution

Mass of water, m=10 g=0.01 kgm = 10 \text{ g} = 0.01 \text{ kg}

Heat required to raise the temperature of water from 0^{}^{{}^{\circ}}\text{C} to 100^{}^{{}^{\circ}}\text{C} is given by:
Q1=mcΔT=0.01×4200×100=4200 JQ_1 = m c \Delta T = 0.01 \times 4200 \times 100 = 4200 \text{ J}

Heat required to convert water at 100^{}^{{}^{\circ}}\text{C} into steam is given by:
Q2=mL=0.01×2.25×106=22500 JQ_2 = mL = 0.01 \times 2.25 \times 10^6 = 22500 \text{ J}

Total heat supplied to the system is:
Q=Q1+Q2=4200+22500=26700 JQ = Q_1 + Q_2 = 4200 + 22500 = 26700 \text{ J}

Work done by the system against the constant external pressure during vaporization is:
W=P(Vsteam−Vwater)W = P(V_{\text{steam}} - V_{\text{water}})

Neglecting the initial volume of water, the volume of steam is:
Vsteam=mρsteam=0.010.6=160 m3V_{\text{steam}} = \dfrac{m}{\rho_{\text{steam}}} = \dfrac{0.01}{0.6} = \dfrac{1}{60} \text{ m}^3

Substituting the values to find the work done:
W=100×103×160=1666.67 JW = 100 \times 10^3 \times \dfrac{1}{60} = 1666.67 \text{ J}

Using the first law of thermodynamics, the increase in internal energy is:
ΔU=Q−W\Delta U = Q - W
ΔU=26700−1666.67=25033.33 J\Delta U = 26700 - 1666.67 = 25033.33 \text{ J}

ΔU≈2.50×104 J\Delta U \approx 2.50 \times 10^4 \text{ J}
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