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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Laws of Thermodynamics

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Laws of Thermodynamics

A cylindrical tube of volume V having adiabatic walls contains an...

A cylindrical tube of volume VV having adiabatic walls contains an ideal gas. The internal energy of this ideal gas is given by 1.5nRT1.5 nRT. A fixed diathermic wall divides the tube into two equal parts. Initially, the pressure and temperature are p1,T1p_1, T_1 on the left side and p2,T2p_2, T_2 on the right side. The system is allowed sufficient time for the temperatures on both sides to become equal. Determine the final equilibrium temperature. (Let λ=p1T2+p2T1\lambda = p_1 T_2 + p_2 T_1)
A cylindrical tube of volume V having adiabatic walls contains an ideal gas. The internal energy of this ideal gas is

Options

  1. AT1T2(p1+p2)p1p2+T1T2\dfrac{T_1 T_2 (p_1 + p_2)}{p_1 p_2 + T_1 T_2}
  2. BT1T2(p1+p2)λ\dfrac{T_1 T_2 (p_1 + p_2)}{\lambda}
  3. CT1T2(p1+p2)p1T1+p2T2\dfrac{T_1 T_2 (p_1 + p_2)}{p_1 T_1 + p_2 T_2}
  4. DT1T2(p1−p2)λ\dfrac{T_1 T_2 (p_1 - p_2)}{\lambda}

Correct answer

B. T1T2(p1+p2)λ\dfrac{T_1 T_2 (p_1 + p_2)}{\lambda}

Step-by-step solution

Let the total volume of the cylindrical tube be VV. Since the diathermic wall divides the tube into two equal parts, the volume of each part is V2\dfrac{V}{2}.

The number of moles of gas in the left and right parts initially are:
n1=p1(V/2)RT1n_1 = \dfrac{p_1 (V/2)}{R T_1}
n2=p2(V/2)RT2n_2 = \dfrac{p_2 (V/2)}{R T_2}

Since the outer walls are adiabatic and the inner wall is fixed, there is no heat exchange with the surroundings (Q=0Q = 0) and no work is done by the system (W=0W = 0). Thus, the total internal energy of the system remains conserved.

Initial internal energy of the system:
Ui=U1+U2=1.5n1RT1+1.5n2RT2U_i = U_1 + U_2 = 1.5 n_1 R T_1 + 1.5 n_2 R T_2
Ui=1.5(p1V2RT1)RT1+1.5(p2V2RT2)RT2U_i = 1.5 \left( \dfrac{p_1 V}{2 R T_1} \right) R T_1 + 1.5 \left( \dfrac{p_2 V}{2 R T_2} \right) R T_2
Ui=1.5V2(p1+p2)U_i = \dfrac{1.5 V}{2} (p_1 + p_2)

Let the final equilibrium temperature be TfT_f. The final internal energy of the system is:
Uf=1.5(n1+n2)RTfU_f = 1.5 (n_1 + n_2) R T_f
Uf=1.5(p1V2RT1+p2V2RT2)RTfU_f = 1.5 \left( \dfrac{p_1 V}{2 R T_1} + \dfrac{p_2 V}{2 R T_2} \right) R T_f
Uf=1.5V2(p1T1+p2T2)TfU_f = \dfrac{1.5 V}{2} \left( \dfrac{p_1}{T_1} + \dfrac{p_2}{T_2} \right) T_f
Uf=1.5V2(p1T2+p2T1T1T2)TfU_f = \dfrac{1.5 V}{2} \left( \dfrac{p_1 T_2 + p_2 T_1}{T_1 T_2} \right) T_f

Equating the initial and final internal energies (Ui=UfU_i = U_f):
1.5V2(p1+p2)=1.5V2(p1T2+p2T1T1T2)Tf\dfrac{1.5 V}{2} (p_1 + p_2) = \dfrac{1.5 V}{2} \left( \dfrac{p_1 T_2 + p_2 T_1}{T_1 T_2} \right) T_f

p1+p2=(p1T2+p2T1T1T2)Tfp_1 + p_2 = \left( \dfrac{p_1 T_2 + p_2 T_1}{T_1 T_2} \right) T_f

Tf=T1T2(p1+p2)p1T2+p2T1T_f = \dfrac{T_1 T_2 (p_1 + p_2)}{p_1 T_2 + p_2 T_1}

Given λ=p1T2+p2T1\lambda = p_1 T_2 + p_2 T_1, we get:
Tf=T1T2(p1+p2)λT_f = \dfrac{T_1 T_2 (p_1 + p_2)}{\lambda}
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