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JEE Main 202227 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
27 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Hydrogen

JEE Main 2022 · 27 July · Morning Shift · Chemistry · Hydrogen

Given below are two statements: Statement I : Hydrogen peroxide can...

Given below are two statements:

Statement I : Hydrogen peroxide can act as an oxidizing agent in both acidic and basic conditions.

Statement II: Density of hydrogen peroxide at 298K298K is lower than that of D2O{D}_{2}O.

In the light of the above statements. Choose the correct answer from the options.

Options

  1. ABoth statement I and Statement II are ture
  2. BBoth statement I and Statement II are false
  3. CStatement I is true but Statement II is false
  4. DStatement I is false but Statement II is true

Correct answer

C. Statement I is true but Statement II is false

Step-by-step solution

It acts as an oxidising as well as reducing agent in both acidic and alkaline media. Simple reactions are described below.

(i) Oxidising action in acidic medium

2Fe2+(aq)+2H+(aq)+H2O2(aq)→2Fe3+(aq)+2H2O(l)2{Fe}^{2 +}\left(aq\right) + 2{H}^{+}\left(aq\right) + {H}_{2}{O}_{2}\left(aq\right) \to 2{Fe}^{3 +}\left(aq\right) + 2{H}_{2}O\left(l\right)

(ii) Reducing action in acidic medium

2MnO4−+6H++5H2O2→2Mn2++8H2O+5O22{MnO}_{4}^{-} + 6{H}^{+} + 5{H}_{2}{O}_{2} \to 2{Mn}^{2 +} + 8{H}_{2}O + 5{O}_{2}

(iii) Oxidising action in basic medium

2Fe2++H2O2→2Fe3++2OH−2{Fe}^{2 +} + {H}_{2}{O}_{2} \to 2{Fe}^{3 +} + 2{OH}^{-}

(iv) Reducing action in basic medium

I2+H2O2+2OH−→2I−+2H2O+O2{I}_{2} + {H}_{2}{O}_{2} + 2{OH}^{-} \to 2{I}^{-} + 2{H}_{2}O + {O}_{2}

The density of hydrogen peroxide is more than that of heavy water

Density of D2O=1.1g/cc{D}_{2}O = 1 . 1g / cc

Density of H2O2=1.45g/cc{H}_{2}{O}_{2} = 1 . 45g / cc

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