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JEE Main 202229 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
29 June
Shift
Morning Shift
Subject
Chemistry
Chapter
Hydrogen

JEE Main 2022 · 29 June · Morning Shift · Chemistry · Hydrogen

Which one of the following reactions indicates the reducing ability...

Which one of the following reactions indicates the reducing ability of hydrogen peroxide in basic medium?

Options

  1. AHOCl+H2O2→H3O++Cl−+O2HOCl + {H}_{2}{O}_{2} \to {H}_{3}{O}^{+} + {Cl}^{-} + {O}_{2}
  2. BPbS+4H2O2→PbSO4+4H2OPbS + 4{H}_{2}{O}_{2} \to {PbSO}_{4} + 4{H}_{2}O
  3. C2MnO4−+3H2O2→2MnO2+3O2+2H2O+2OH−2{MnO}_{4}^{-} + 3{H}_{2}{O}_{2} \to 2{MnO}_{2} + 3{O}_{2} + 2{H}_{2}O + 2{OH}^{-}
  4. DMn2++H2O2→Mn4++2OH−{Mn}^{2 +} + {H}_{2}{O}_{2} \to {Mn}^{4 +} + 2{OH}^{-}

Correct answer

C. 2MnO4−+3H2O2→2MnO2+3O2+2H2O+2OH−2{MnO}_{4}^{-} + 3{H}_{2}{O}_{2} \to 2{MnO}_{2} + 3{O}_{2} + 2{H}_{2}O + 2{OH}^{-}

Step-by-step solution

In option (A)\left(A\right) and (C)\left(C\right) reducing action of hydrogen peroxide is shown.

For reducing ability H2O2{H}_{2}{O}_{2} changes to O2{O}_{2}, i.e. oxidize, so in option 'AA' & C ' ' {O}_{2}is formed but 'AA' is in acidic medium so option - CC is correct.

2MnO4−+3H2O2→2MnO2+3O2+2H2O+2OH−2{MnO}_{4}^{-} + 3{H}_{2}{O}_{2} \to 2{MnO}_{2} + 3{O}_{2} + 2{H}_{2}O + 2{OH}^{-}

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