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JEE Main 202118 MarchEvening Shift
Exam
JEE Main
Year
2021
Date
18 March
Shift
Evening Shift
Subject
Chemistry
Chapter
Hydrogen

JEE Main 2021 · 18 March · Evening Shift · Chemistry · Hydrogen

In basic medium, H _ 2 O _ 2 exhibits which of the following...

In basic medium, H2O2{H}_{2}{O}_{2} exhibits which of the following reactions?
(A) Mn2+→Mn4+{Mn}^{2 +} \to {Mn}^{4 +}
(B) I2→I−{I}_{2} \to {I}^{-}
(C) PbS→PbSO4PbS \to {PbSO}_{4}
Choose the most appropriate answer from the options given below :

Options

  1. A(A),(C) only
  2. B(A) only
  3. C(B) only
  4. D(A), (B) only

Correct answer

D. (A), (B) only

Step-by-step solution

In basic medium, oxidising action of H2O2{H}_{2}{O}_{2}.

Mn2++H2O2→Mn+4+2OH−{Mn}^{2 +} + {H}_{2}{O}_{2} \to {Mn}^{+ 4} + 2{OH}^{-}

In basic medium, reducing action of H2O2{H}_{2}{O}_{2}

I2+H2O2+2OH−→2I−+2H2O+O2{I}_{2} + {H}_{2}{O}_{2} + 2{OH}^{-} \to 2{I}^{-} + 2{H}_{2}O + {O}_{2}

In acidic medium, oxidising action of H2O2{H}_{2}{O}_{2}

PbS(s)+4H2O2(aq)→PbSO4(s)+4H2O(l)PbS ( s ) + 4{H}_{2}{O}_{2} ( aq ) \to {PbSO}_{4} ( s ) + 4{H}_{2}O ( l )

Hence correct option (4)( 4 ).

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