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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Thermal and Chemical Effects of Electric Current

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Thermal and Chemical Effects of Electric Current

An electrolysis experiment is halted, and the connections to the...

An electrolysis experiment is halted, and the connections to the battery terminals are subsequently reversed.

Options

  1. AHeat will be generated at an increased rate.
  2. BThe electrolysis process will cease.
  3. CThe rate of material liberation will remain unchanged.
  4. DThe rate at which material is liberated at the electrodes will increase.

Correct answer

D. The rate at which material is liberated at the electrodes will increase.

Step-by-step solution

During electrolysis, a back EMF ee is developed in the cell due to the accumulation of products at the electrodes, which opposes the applied EMF EE.

The effective EMF in the circuit is E−eE - e, and the initial current is I1=E−eRI_1 = \dfrac{E - e}{R}, where RR is the resistance of the circuit.

When the battery terminals are reversed, the applied EMF EE and the back EMF ee act in the same direction. The new effective EMF becomes E+eE + e.

The new current in the circuit is I2=E+eRI_2 = \dfrac{E + e}{R}.

Since I2>I1I_2 > I_1, the magnitude of the current in the circuit increases.

The rate of heat generation is given by I2RI^2 R. As the current increases, heat will be generated at an increased rate.

According to Faraday's first law of electrolysis, the rate of material liberation is dmdt=ZI\dfrac{dm}{dt} = ZI. Since the current increases, the rate at which material is liberated at the electrodes will also increase.
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