Concepts Of Physics MCQ Edition [Volume 2]
- Exam
- Concepts Of Physics MCQ Edition [Volume 2]
- Subject
- Physics
- Chapter
- Thermal and Chemical Effects of Electric Current
Concepts Of Physics MCQ Edition [Volume 2] · Physics · Thermal and Chemical Effects of Electric Current
An electrolysis experiment is halted, and the connections to the...
An electrolysis experiment is halted, and the connections to the battery terminals are subsequently reversed.
Options
- AHeat will be generated at an increased rate.
- BThe electrolysis process will cease.
- CThe rate of material liberation will remain unchanged.
- DThe rate at which material is liberated at the electrodes will increase.
Correct answer
D. The rate at which material is liberated at the electrodes will increase.
Step-by-step solution
During electrolysis, a back EMF is developed in the cell due to the accumulation of products at the electrodes, which opposes the applied EMF .
The effective EMF in the circuit is , and the initial current is , where is the resistance of the circuit.
When the battery terminals are reversed, the applied EMF and the back EMF act in the same direction. The new effective EMF becomes .
The new current in the circuit is .
Since , the magnitude of the current in the circuit increases.
The rate of heat generation is given by . As the current increases, heat will be generated at an increased rate.
According to Faraday's first law of electrolysis, the rate of material liberation is . Since the current increases, the rate at which material is liberated at the electrodes will also increase.
The effective EMF in the circuit is , and the initial current is , where is the resistance of the circuit.
When the battery terminals are reversed, the applied EMF and the back EMF act in the same direction. The new effective EMF becomes .
The new current in the circuit is .
Since , the magnitude of the current in the circuit increases.
The rate of heat generation is given by . As the current increases, heat will be generated at an increased rate.
According to Faraday's first law of electrolysis, the rate of material liberation is . Since the current increases, the rate at which material is liberated at the electrodes will also increase.