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JEE Main 20198 AprilMorning Shift
Exam
JEE Main
Year
2019
Date
8 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Hydrogen

JEE Main 2019 · 8 April · Morning Shift · Chemistry · Hydrogen

100mL of a water sample contains 0.81g of calcium bicarbonate and...

100mL100mL of a water sample contains 0.81g0.81g of calcium bicarbonate and 0.730.73 g of magnesium bicarbonate. The hardness of this water sample expressed in terms of equivalents of CaCO3CaC{O}_{3} is:
(molar mass of calcium bicarbonate is 162gmmol−1162gmmo{l}^{- 1} and magnesium bicarbonate is 146gmol−1)146gmo{l}^{- 1} )

Options

  1. A100ppm100ppm
  2. B1,000ppm1,000ppm
  3. C5,000ppm5,000ppm
  4. D10,000ppm10,000ppm

Correct answer

D. 10,000ppm10,000ppm

Step-by-step solution

neqCaCO3=neqCa(HCO3)2+neqMg(HCO3)2{n}_{eq}CaC{O}_{3} = {n}_{eq}Ca{\left(HC{O}_{3}\right)}_{2} + {n}_{eq}Mg{\left(HC{O}_{3}\right)}_{2}
or, W100×2=0.81162×2+0.73146×2\dfrac{W}{100} \times 2 = \dfrac{0.81}{162} \times 2 + \dfrac{0.73}{146} \times 2
∴W=1.0∴ W = 1.0
∴∴ Hardness =1.0100×106=10000ppm= \dfrac{1.0}{100} \times {10}^{6} = 10000ppm
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