Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main
Exam
JEE Main
Subject
Chemistry
Chapter
Redox Reactions

JEE Main · Chemistry · Redox Reactions

Balance the following equations in basic medium by ion - electron...

Balance the following equations in basic medium by ion - electron method and oxidation number methods

{Cl2O7(g)+H2O2(aq)⟶ClO2−(aq)+O2(g)\begin{cases}{Cl}_{2} {O}_{7} \left(\text{g}\right) + {H}_{2} {O}_{2} \left(\text{aq}\right) & ⟶ & {ClO}_{2}^{-} \left(\text{aq}\right) + {O}_{2} \left(\text{g}\right)\end{cases}~ stoichiometric coefficients for Cl2O7(g), H2O2(aq), ClO2−{ClO}_{2}^{-} and O2(g) may be

Options

  1. A1, 4, 2, 4
  2. B1, 3, 2, 3
  3. C1, 5, 2, 4
  4. D1, 2, 2, 2

Correct answer

A. 1, 4, 2, 4

Step-by-step solution

\begin{cases}{\overset{+ 7}{Cl}}_{2} {O}_{7} + 8 \text{e} & ⟶ & 2 \overset{+ 3}{Cl} {O}_{2}^{- 1} & \left[\text{RHR}\right] \\ {H}_{2} {O}_{2} + 2 {OH}_{aq}^{- 1} & ⟶ & \text{O} + 2 {H}_{2} \text{O} + 2 e^{-} & \left[\text{OHR}\right] } × 4\end{cases}
------------------------------------------------------------------------
{Cl2O7+4H2O2+8OHaq−⟶2ClO2aq−1+4O2+8H2O\begin{cases}{Cl}_{2} {O}_{7} + 4 {H}_{2} {O}_{2} + 8 {OH}_{aq}^{-} & ⟶ & 2 {ClO}_{2 \text{aq}}^{- 1} + 4 {O}_{2} + 8 {H}_{2} \text{O}\end{cases}

To balance unbalanced oxygen atoms, add 3H2O molecules on LHS and 6 OH- ions on RHS

{Cl2O7+4H2O2+8OH−+3H2O⟶2ClO2−1+4O2+8H2O+6OHaq−1\begin{cases}{Cl}_{2} {O}_{7} + 4 {H}_{2} {O}_{2} + 8 {OH}^{-} + 3 {H}_{2} \text{O} & ⟶ & 2 {ClO}_{2}^{- 1} + 4 {O}_{2} + 8 {H}_{2} \text{O} + 6 {OH}_{aq}^{- 1}\end{cases}

{Cl2O7+4H2O2+2OHaq−1⟶2ClO2−1+4O2+5H2O\begin{cases}{Cl}_{2} {O}_{7} + 4 {H}_{2} {O}_{2} + 2 {OH}_{aq}^{- 1} & ⟶ & 2 {ClO}_{2}^{- 1} + 4 {O}_{2} + 5 {H}_{2} \text{O}\end{cases}
Practice Redox Reactions on Quantrex Academy →

More from Redox Reactions

500 mL of 0.2 M MnO _4^- solution in basic medium when mixed with 500 mL of 1.5 M KI… JEE Main 2026Given below are two statements: Statement I: Sodium dichromate and potassium dichromate… JEE Main 2026In order to oxidise a mixture of 1 mole each of FeC_2O_4 , Fe_2(C_2O_4)_3 , FeSO_4 and… JEE Main 2026500 mL of 1.2 M KI solution is mixed with 500 mL of 0.2 M KMnO_ 4 solution in basic… JEE Main 2026One mole of Cl_ 2 (~g) was passed into 2 L of cold 2 M KOH solution. After the reaction… JEE Main 2026X and Y are the number of electrons involved, respectively during the oxidation of I^… JEE Main 2026200 cc of x × 10^ -3 M potassium dichromate is required to oxidise 750 cc of 0.6 M Mohr's… JEE Main 2026Identify the correct statements : A. Hydrated salts can be used as primary standard. B.… JEE Main 2026 Full Redox Reactions list All Highly selective Backlog Qs for JEE Main PYQs