Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
Most Important Selected Qs for JEE AdvancedChemistryElectrochemistry

Consider the electrochemical cell aligned & Zn | Zn _ 0.01 M , 1 ~L ^ LL _ 0.11 Ag ^ +1 ~L | Ag & E _ Ag ⁺ / Ag ^ =0.8 ~V & E _ Zn ⁺² / Zn ^ =-0.77 ~V aligned If x ~L of H ₂ O is added in anodic chamber and y ~L of H ₂ O is added in cathodic chamber such that emf of cell is more than E_ c e l l ^ . The possible value of x and y are

Options

  1. A90 10
  2. B25 4
  3. C31 5
  4. D13 3

Correct answer

B. 25 4

Step-by-step solution

Hint : E = E ^ + 0.059 2 [ Ag ⁺ ]^2 [ Zn ]^2 Solution : aligned & E = E ^ + 0.059 2 ( 0.1 ~V ₁ )^2 ( 0.01 ~V ₂ ) & E = E ^ + 0.059 2 ~V ₂ ~V ₁^2 & E E ^ , V ₂ V ₁^2 & (1+ x ) (1+ y )^2 aligned V₁ volume of solution of cathode chamber. V ₂ volume of solution of Anode chamber.

Practice Electrochemistry on Quantrex Academy →

More from Electrochemistry

At 300 K, the molar conductivities of the aqueous solutions of three salts at two different concentrations are given below: Salt Concentration (M) Molar conductivity (S cm ^2 mol ⁻ 2026Given at 298 K: E^ _ Fe²⁺/Fe = X Volt; E^ _ Fe³⁺/Fe = Y Volt. The E^ _ Fe³⁺/Fe²⁺ in Volt at 298 K is given by: 2026For a general redox reaction Anode : Red ₁ Ox ₁^ n₁^+ + n₁ e^- Cathode : Ox ₂ + n₂ e^- Red ₂^ n₂^- Which of the following statements is incorrect? 2026Consider the following data. Electrolyte ^ _m (S cm ^2 mol ⁻¹ ) BaCl ₂ x₁ H ₂ SO ₄ x₂ HCl x₃ BaSO ₄ is sparingly soluble in water. If the conductivity of the saturated BaSO ₄ solut 2026One half cell in a voltaic cell is constructed by dipping silver rod in AgNO₃ solution of unknown concentration, other half cell is Zn rod dipped in 1 molar solution of ZnSO₄ . A v 2026At 298 K , the molar conductivity of x % (w/w) MX solution (aqueous) is 123.5 S cm ^2 mol ⁻¹ . The conductance of same solution is 1.9 10⁻³ S . The value of x is _______ 10⁻² . (Gi 2026An electrochemical cell, consist of the following two redox couples, M^ x+ (aq)/M(s)[E_ red ^ =+0.15 V ] and Fe³⁺(aq)/Fe(s)[E_ red ^ =-0.036 V ] . The cell EMF (E_ cell ) is record 2026Consider the following two half-cell reactions along with the standard reduction potential given: CO₂ + 6H^+ + 6e^- CH₃ OH + H₂ O E°_ red = 0.02 V 1 2 O₂ + 2H^+ + 2e^- H₂ O E°_ red 2026 Full Electrochemistry list All Most Important Selected Qs for JEE Advanced PYQs