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JEE Advanced
Exam
JEE Advanced
Subject
Chemistry
Chapter
Hydrogen

JEE Advanced · Chemistry · Hydrogen

An aqueous solution of X on addition of hydrogen peroxide in ice...

An aqueous solution of XX on addition of hydrogen peroxide in ice cold conditions gives blue colour to the ethereal layer. Then, XX can be

Options

  1. Aacidified potassium chromate
  2. Balkaline potassium dichromate
  3. Cacidified potassium manganate
  4. Dacidified potassium permanganate

Correct answer

A. acidified potassium chromate

Step-by-step solution

Both chromate and dichromate radicals on reaction with acidified H2O2\mathrm{H}_{2} \mathrm{O}_{2} give blue solution which turns green on standing. In the presence of organic solvents such as diethyl ether, amyl alcohol or pyridine, permanent blue colour obtained.
K2Cr2O4+H2SO4+H2O2⟶ Ether CrO5+K2SO4+K2Cr2O7+4H2SO4+4H2O2⟶ Ether 2CrO5 (Blue colour) +K2SO4+5H2O\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{4}+\mathrm{H}_{2} \mathrm{SO}_{4}+\mathrm{H}_{2} \mathrm{O}_{2} \stackrel{\text { Ether }}{\longrightarrow} \mathrm{CrO}_{5}+\mathrm{K}_{2} \mathrm{SO}_{4} +\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}+4 \mathrm{H}_{2} \mathrm{SO}_{4}+4 \mathrm{H}_{2} \mathrm{O}_{2} \stackrel{\text { Ether }}{\longrightarrow} \underset{\text { (Blue colour) }}{2 \mathrm{CrO}_{5}}+\mathrm{K}_{2} \mathrm{SO}_{4} +5 \mathrm{H}_{2} \mathrm{O}
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