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JEE Main 202229 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
29 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2022 · 29 June · Evening Shift · Chemistry · Redox Reactions

For the reaction given below: CoCl _ 3 . xNH _ 3 + AgNO _ 3 (aq) →...

For the reaction given below:

CoCl3.xNH3+AgNO3(aq)→{CoCl}_{3} . {xNH}_{3} + {AgNO}_{3}\left(aq\right) \to

If two equivalents of AgClAgCl precipitate out, then the value of xx will be _______

Correct answer

0

Step-by-step solution

{CoCl}_{3 .}{xNH}_{3} + {AgNO}_{3} \to \mathop{AgCl ↓}_{2mol}</p><p>For2molesofAgClprecipitateout,onlytwochlorideionsshouldbepresentoutsidethecoordinationspherethatisintheionizationsphere.</p><p>Hence,theformulaofthecomplexshouldbe</p><p>For 2 moles of AgCl precipitate out,only two chloride ions should be present out side the coordination sphere that is in the ionization sphere.</p><p>Hence, the formula of the complex should be\left[Co{\left({NH}_{3}\right)}_{5}Cl\right]{Cl}_{2}</p><p>[Co(NH3)5Cl]Cl2+AgNO3→AgCl↓2mol</p><p>\left[Co{\left({NH}_{3}\right)}_{5}Cl\right]{Cl}_{2} + {AgNO}_{3} \to \mathop{AgCl ↓}_{2mol}

So, the value of x should be 5.

x=5x = 5.

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