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Olympiad workbookNSECChemical Kinetics

Gas phase reactions (i) and (ii) are of first and second order respectively aligned & 2 ~N ₂ O ₅ 4 NO ₂+ O ₂ (i) & 2 NO + O ₂ 2 NO ₂ (ii) aligned Under certain conditions, the rate constants ( k ₁, k ₂ ) of (i) and (ii) respectively, have the same numerical value, when the concentrations of the reactants are expressed in mol / dm ^3 . If the concentrations are expressed in mol / mL , the correct relationship between

Options

  1. Ak ₂ 10⁻³= k ₁
  2. Bk ₂ 10^3= k ₁
  3. Ck ₁= k ₂
  4. Dk ₁ 10^6= k ₂

Correct answer

A. k ₂ 10⁻³= k ₁

Step-by-step solution

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