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JEE Main 20204 SeptemberMorning Shift
Exam
JEE Main
Year
2020
Date
4 September
Shift
Morning Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2020 · 4 September · Morning Shift · Chemistry · Redox Reactions

A 20 . 0mL solution containing 0 . 2g impure H _ 2 O _ 2 reacts...

A 20.0mL20 . 0mL solution containing 0.2g0 . 2g impure H2O2{H}_{2}{O}_{2} reacts completely with 0.316g0 . 316g of KMnO4{KMnO}_{4} in acid solution. The purity of H2O2{H}_{2}{O}_{2} (in %) is______ (mol. wt. of H2O2=34{H}_{2}{O}_{2} = 34; mol. wt. of KMnO4=158{KMnO}_{4} = 158)

Correct answer

0

Step-by-step solution

Let mass of pure H2O2{H}_{2}{O}_{2} is xx gram

+7MnO4−\begin{array}{ll}+ 7 \\ MnO{4}^{-}\end{array}+\begin{array}{ll}+\end{array}−1H2O2vf=2\begin{array}{ll}- 1 \\ {H}_{2}{O}_{2} \\ vf = 2\end{array}→\begin{array}{ll}\to\end{array}+2Mn2+\begin{array}{ll}+ 2 \\ {Mn}^{2 +}\end{array}+\begin{array}{ll}+\end{array}0O2\begin{array}{ll}0 \\ {O}_{2}\end{array}

Eq. of H2O2=Eq.{H}_{2}{O}_{2} = Eq . of MnO4−MnO{4}^{-}

\left[\dfrac{x}{34}\right]2 = \left[\dfrac{0 .316}{158}\right]5</p><p></p><p>x = 0 . 17</p><p>So,</p><p>So,%purityofpurity of{H}_{2}{O}_{2}solutionsolution= \dfrac{0 .17}{0 .2} \times 100 = 85 %$

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