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JEE Main 20198 AprilMorning Shift
Exam
JEE Main
Year
2019
Date
8 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2019 · 8 April · Morning Shift · Chemistry · Redox Reactions

In order to oxidize a mixture of one mole of each of Fe C _ 2 O _ 4...

In order to oxidize a mixture of one mole of each of FeC2O4,Fe2(C2O4)3,FeSO4Fe{C}_{2}{O}_{4}, F{e}_{2}{( {C}_{2}{O}_{4} )}_{3}, FeS{O}_{4} and Fe2(SO4)3F{e}_{2}{( S{O}_{4} )}_{3} in acidic medium, the number of moles of KMnO4KMn{O}_{4} is:In order to oxidize a mixture of one mole of each of Fe C _ 2 O _ 4 , F e _ 2 ( C _ 2 O _ 4 ) _ 3 , FeS O _ 4 and F e _

Options

  1. A11
  2. B22
  3. C33
  4. D1.51.5

Correct answer

B. 22

Step-by-step solution

Eq.KMnO4⇒Eq.FeSO4+Eq.Fe2(SO4)3+EqFeC2O4+Eq.Fe2(C2O4)3Eq . KMn{O}_{4} ⇒ Eq . FeS{O}_{4} + Eq . F{e}_{2}{\left(S{O}_{4}\right)}_{3} + EqFe{C}_{2}{O}_{4} + Eq . F{e}_{2}{\left({C}_{2}{O}_{4}\right)}_{3}
KMnO4⇒MnO4−KMn{O}_{4} ⇒ Mn{O}_{4}^{-}
5e−+8H++MnO4−⇒Mn+2+4H2O5{e}^{-} + 8{H}^{+} + Mn{O}_{4}^{-} ⇒ M{n}^{+ 2} + 4{H}_{2}O V.F=5\text{V.F} = 5
In order to oxidize a mixture of one mole of each of Fe C _ 2 O _ 4 , F e _ 2 ( C _ 2 O _ 4 ) _ 3 , FeS O _ 4 and F e _
So Eq.KMnO4⇒Eq.FeSO4+Eq.FeC2O4+Eq.Fe2(C2O4)3Eq . KMn{O}_{4} ⇒ Eq . FeS{O}_{4} + Eq . Fe{C}_{2}{O}_{4} + Eq . F{e}_{2}{\left({C}_{2}{O}_{4}\right)}_{3}
n×5=1×1+1×0+1×3+1×6n \times 5 = 1 \times 1 + 1 \times 0 + 1 \times 3 + 1 \times 6
n×5=1+3+6n \times 5 = 1 + 3 + 6
n=105=2molen = \dfrac{10}{5} = 2mole
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