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JEE Main 202329 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
29 January
Shift
Morning Shift
Subject
Chemistry
Chapter
s Block Elements

JEE Main 2023 · 29 January · Morning Shift · Chemistry · s Block Elements

The correct order of hydration enthalpies is (A) K ^ + (B) Rb ^ +...

The correct order of hydration enthalpies is

(A) K+{K}^{+}
(B) Rb+{Rb}^{+}
(C) Mg2+{Mg}^{2 +}
(D) Cs+{Cs}^{+}
(E) Ca2+{Ca}^{2 +}

Choose the correct answer from the options given below:

Options

  1. AC > A > E > B > D
  2. BE > C > A > B > D
  3. CC > E > A > D > B
  4. DC > E > A > B > D

Correct answer

D. C > E > A > B > D

Step-by-step solution

The hydration enthalpy of alkali metal ions decreases with an increase in ionic sizes.

So, the order is: Li+>Na+>K+>Rb+>Cs+{Li}^{+} > {Na}^{+} > {K}^{+} > {Rb}^{+} > {Cs}^{+}

Like alkali metal ions, the hydration enthalpies of alkaline earth metal ions decrease with an increase in ionic size down the group.

So, the order is: Be2+>Mg2+>Ca2+>Sr2+>Ba2+{Be}^{2 +} > {Mg}^{2 +} > {Ca}^{2 +} > {Sr}^{2 +} > {Ba}^{2 +}

The hydration enthalpies of alkaline earth metal ions are larger than those of alkali metal ions.

So, the correct order is: Mg2+>Ca2+>K+>Rb+>Cs+{Mg}^{2 +} > {Ca}^{2 +} > {K}^{+} > {Rb}^{+} > {Cs}^{+}

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