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JEE Main 202622 JanuaryEvening Shift
Exam
JEE Main
Year
2026
Date
22 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2026 · 22 January · Evening Shift · Chemistry · Solutions

At T(K), 100 ~g of 98 \% H_ 2 SO_ 4 (w / w) aqueous solution is...

At T(K),100 g\mathrm{T}(\mathrm{K}), 100 \mathrm{~g} of 98%H2SO4(w/w)98 \% \mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{w} / \mathrm{w}) aqueous solution is mixed with 100 g of 49%H2SO4(w/w)49 \% \mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{w} / \mathrm{w}) aqueous solution. What is the mole fraction of H2SO4\mathrm{H}_{2} \mathrm{SO}_{4} in the resultant solution?
(Given : Atomic mass H=1u;S=32u;O=16u\mathrm{H}=1 \mathrm{u} ; \mathrm{S}=32 \mathrm{u} ; \mathrm{O}=16 \mathrm{u}).
(Assume that temperature after mixing remains constant)

Options

  1. A0.663
  2. B0.9
  3. C0.337
  4. D0.1

Correct answer

C. 0.337

Step-by-step solution

Molar mass of H₂SO₄ = 98 g/mol.
Solution 1: 100 g at 98% gives 98 g H₂SO₄ = 1 mol; water = 2 g = 0.111 mol.
Solution 2: 100 g at 49% gives 49 g H₂SO₄ = 0.5 mol; water = 51 g = 2.833 mol.
Mixed solution: Total H₂SO₄ = 1 + 0.5 = 1.5 mol.
Total water = 0.111 + 2.833 = 2.944 mol.
Mole fraction of H₂SO₄ = 1.5/(1.5 + 2.944) = 1.5/4.444 = 0.337.
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