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JEE Main 20257 AprilEvening Shift
Exam
JEE Main
Year
2025
Date
7 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2025 · 7 April · Evening Shift · Chemistry · Solutions

Liquid A and B form an ideal solution. The vapour pressure of pure...

Liquid A and B form an ideal solution. The vapour pressure of pure liquids A and B are 350 and 750 mm Hg respectively at the same temperature. If xA\mathrm{x}_{\mathrm{A}} and xBx_B are the mole fraction of AA and BB in solution while yAy_A and yBy_B are the mole fraction of A and B in vapour phase then :

Options

  1. AxAxB<yAyB\frac{\mathrm{x}_{\mathrm{A}}}{\mathrm{x}_{\mathrm{B}}} \lt \frac{\mathrm{y}_{\mathrm{A}}}{\mathrm{y}_{\mathrm{B}}}
  2. BxAxB=yAyB\frac{\mathrm{x}_{\mathrm{A}}}{\mathrm{x}_{\mathrm{B}}}=\frac{\mathrm{y}_{\mathrm{A}}}{\mathrm{y}_{\mathrm{B}}}
  3. CxAxB>yAyB\frac{\mathrm{x}_{\mathrm{A}}}{\mathrm{x}_{\mathrm{B}}} \gt \frac{\mathrm{y}_{\mathrm{A}}}{\mathrm{y}_{\mathrm{B}}}
  4. D(xA−yA)<(xB−yB)\left(\mathrm{x}_{\mathrm{A}}-\mathrm{y}_{\mathrm{A}}\right) \lt \left(\mathrm{x}_{\mathrm{B}}-\mathrm{y}_{\mathrm{B}}\right)

Correct answer

C. xAxB>yAyB\frac{\mathrm{x}_{\mathrm{A}}}{\mathrm{x}_{\mathrm{B}}} \gt \frac{\mathrm{y}_{\mathrm{A}}}{\mathrm{y}_{\mathrm{B}}}

Step-by-step solution

PAo<PBoPAoPBo<1yAyB=PAoPBoxAxByAyBxAxB\begin{aligned} & \mathrm{P}_{\mathrm{A}}^{\mathrm{o}} \lt \mathrm{P}_{\mathrm{B}}^{\mathrm{o}} \\ & \frac{\mathrm{P}_{\mathrm{A}}^o}{\mathrm{P}_{\mathrm{B}}^o} \lt 1 \\ & \frac{\mathrm{y}_{\mathrm{A}}}{\mathrm{y}_{\mathrm{B}}}=\frac{\mathrm{P}_{\mathrm{A}}^o}{\mathrm{P}_{\mathrm{B}}^o} \frac{\mathrm{x}_{\mathrm{A}}}{\mathrm{x}_{\mathrm{B}}} \\ & \frac{\mathrm{y}_{\mathrm{A}}}{\mathrm{y}_{\mathrm{B}}} \\ & \frac{\mathrm{x}_{\mathrm{A}}}{\mathrm{x}_{\mathrm{B}}}\end{aligned}
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